Metal Particle Layer for Light Extraction Efficiency

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Solution Overview

Problem

Sapphire substrate-free vertical LEDs exhibit lower light extraction efficiency due to total reflection of light at the interface between gallium nitride and molding materials with different refractive indices, necessitating improved methods for enhancing light emission.

Innovation Solution

A method for forming a metal particle layer with irregular structures by oxidizing a base in an activation solution containing a metal compound, organic acid activator, and complexing agent, which deposits metal particles on the surface, thereby improving light extraction efficiency in light emitting devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of stationary object

If a sapphire substrate-free vertical LED structure is used, then the light emission area increases and fabrication is simplified, but light extraction efficiency decreases due to total internal reflection at the gallium nitride-molding material interface

Engineering Contradiction:
Improvelight emission areaVSAvoidlight extraction efficiency
Core Design Contradiction:
Area of stationary objectVSLoss of energy

Solution Approach 1:

The patent applies local quality by creating nanosized irregular structures (protrusions and recesses) on specific regions of the electrode layer surface. These localized structural modifications are formed through selective metal particle deposition using a dip-pen nanolithography method, where conductive ink is deposited in predetermined patterns to create irregularities only in specific areas, thereby reducing total internal reflection at critical interface regions without modifying the entire device structure

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent transitions from a two-dimensional flat electrode layer surface to a three-dimensional surface with nanosized irregular structures. By adding vertical dimensionality through protrusions and recesses (height variations of 1-100 nm), the light extraction efficiency is improved as these three-dimensional structures disrupt total internal reflection at the gallium nitride-molding material interface

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Ease of manufacture

If conventional metal layers with flat surfaces are used, then the fabrication process is simple, but light extraction efficiency is poor due to total internal reflection

Engineering Contradiction:
Improvefabrication simplicityVSAvoidlight extraction efficiency
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent employs a self-service approach by using a dip-pen nanolithography method where the system uses itself to create the desired pattern. The conductive ink solution is deposited directly from a dip-coating process, and the metal particles self-organize and self-align during deposition, eliminating the need for complex photolithography masks or electron beam patterning equipment

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces complex mechanical fabrication systems (such as photolithography equipment, etching tools, and multiple deposition chambers) with a simple liquid-phase deposition process. The irregular structures are formed by dipping the substrate into a metal particle solution, allowing metal particles to deposit selectively on the electrode layer surface without requiring sophisticated mechanical or optical fabrication equipment

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The metal particle layer with nanosized irregular structures reduces total internal reflection, resulting in enhanced light extraction efficiency and improved thermal dissipation characteristics in light emitting devices.

Implementation Method 1

the base is oxidized by the organic acid activator to produce electrons

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

the metal compound is reduced by the electrons to deposit metal particles on the surface of the base

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 3

the base is oxidized by the organic acid activator to produce electrons and the metal compound is reduced by the electrons

Methodology Applied
Scientific EffectRedox Reactions: Redox Reactions

Implementation Method 4

a large difference in refractive index between gallium nitride (GaN) and the molding material causes total reflection of a considerable portion of light from the LED structure

Methodology Applied
Scientific EffectTotal internal reflection: Total Internal Reflection

Implementation Method 5

The metal particle layer with nanosized irregular structures reduces total internal reflection

Methodology Applied
Scientific EffectScattering: Scattering

Data Source

PatentUS10161046B2Method for forming metal particle layer and light emitting device fabricated using metal particle layer formed by the method
Publication Date: 2018.12.25 LG CHEM LTD
  • US10161046B2 patent drawing
  • US10161046B2 patent drawing
  • US10161046B2 patent drawing

AI summary

Disclosed is a method for forming a metal particle layer having irregular structures in a simpler manner. The method includes bringing a base into contact with an activation solution including a metal compound, an organic acid activator, and a complexing agent. The base is oxidized by the organic acid activator to produce electrons and the metal compound is reduced by the electrons to deposit metal particles on the surface of the base. Also disclosed is a method for fabricating a light emitting device with improved light extraction efficiency that uses a metal particle layer formed by the above method.