Metal-Crosslinkable Polymer Coating for Fast Heat-Triggered Curing

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Solution Overview

Problem

Existing adhesive and curing molding materials face challenges with slow curing times, oxygen sensitivity, and storage stability issues, particularly in areas with limited light exposure.

Innovation Solution

A metal-crosslinkable polymer composition comprising ingredient A, which releases a metal ion upon heating, and ingredient B, an organic polymer with a substituent group capable of forming an ionic bond with the metal ion, resulting in a crosslinked polymeric material with enhanced curing rate and storage stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If moisture curable material, cationic curable material, anionic curable material, or thermosetting material is used, then storage stability is maintained, but curing time becomes excessively long

Engineering Contradiction:
Improvestorage stabilityVSAvoidcuring time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent applies preliminary action by incorporating a metal ion-releasing agent into the composition before use. This agent is designed to release metal ions only when heated to a specific temperature, which triggers the crosslinking reaction. The preliminary preparation of the composition allows it to remain stable during storage, while the pre-included metal ion-releasing mechanism ensures rapid curing once the temperature condition is met, thus resolving the contradiction between storage stability and curing time.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If photocurable material is used, then curing speed is improved, but curing in areas with limited light exposure becomes difficult

Engineering Contradiction:
Improvecuring speedVSAvoidcuring applicability in limited light areas
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The patent replaces the optical mechanism (light-induced photopolymerization) with a thermal mechanism (heat-induced metal ion release and crosslinking). Instead of using photoinitiators that require light exposure, the composition uses a metal ion-releasing agent that responds to thermal energy. This substitution allows the material to cure at high speed regardless of light availability, making it adaptable to areas with limited light exposure while maintaining fast curing performance.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If anaerobic curable material is used, then curing speed is improved, but oxygen blocking is required during curing

Engineering Contradiction:
Improvecuring speedVSAvoidoxygen blocking requirement
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent changes the triggering parameter for curing from oxygen exclusion (chemical environment control) to temperature (thermal energy input). By using a metal ion-releasing agent that activates at a specific temperature, the curing process becomes independent of oxygen presence. This parameter change eliminates the need for complex oxygen blocking measures while maintaining fast curing speed, as the thermal activation mechanism proceeds regardless of atmospheric conditions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves fast curing and maintains stability during storage, providing excellent adhesion and corrosion resistance in metal members and wiring harnesses.

Implementation Method 1

an ingredient A which releases a metal ion when heated

Methodology Applied
Scientific EffectThermal decomposition: Decomposition (biological)

Implementation Method 2

an organic polymer having a substituent group capable of forming an ionic bond with the metal ion

Methodology Applied
Scientific EffectIonic bonding: Chemical Bonding

Data Source

PatentUS12435202B2Metal-crosslinkable polymer composition, metal-crosslinked polymeric material, metal component, and wiring harness
Publication Date: 2025.10.07 AUTONETWORKS TECH LTD
  • US12435202B2 patent drawing
  • US12435202B2 patent drawing
  • US12435202B2 patent drawing

AI summary

A metal-crosslinkable polymer composition and a metal crosslinked polymeric material having excellent curing rate and storage stability, and a metal member and a wiring harness to which the metal-crosslinkable polymer composition and the metal crosslinked polymeric material are applied. The metal-crosslinkable polymer composition includes an ingredient A which releases a metal ion when heated, and an ingredient B includes an organic polymer having a substituent group capable of forming an ionic bond with the metal ion released from the ingredient A. The metal-crosslinked polymeric material includes a crosslinked product of the metal-crosslinkable polymer composition. The metal member has a metal base member and a coating member covering a surface of the metal base member, where the coating member includes the metal-crosslinked polymeric material. The wiring harness includes the metal-crosslinked polymeric material.