Metal-Polymer Composite Mirror Surface via Photochemical Synthesis

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing metal-polymer composite materials with metallic particles do not consistently produce an electronically conducting layer or a reflective metallic surface, and their production methods are costly and not environmentally friendly, especially for industrial-scale applications.

Innovation Solution

A photo-assisted method for in situ synthesis of metal nanoparticles in a photopolymerizable matrix, coupling photopolymerizing kinetics with photo-reducing kinetics to create a composite material with a higher concentration of metallic particles at the surface, forming an electronically conducting and reflective metallic mirror layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional methods are used to produce metal-polymer composite materials with metallic particles, then the material contains metallic particles, but the material does not consistently produce an electronically conducting layer or reflective metallic surface

Engineering Contradiction:
Improveconsistency of electronically conducting layer formationVSAvoidproduction efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention changes the concentration parameter of metallic particles in the composite material. By increasing the metallic particle concentration to at least 60% by weight, the material transitions from inconsistent electrical conductivity to reliable electronic conduction and reflective metallic surface formation. This parameter change directly resolves the reliability issue while maintaining production efficiency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a specific composite material structure where metallic particles are embedded in a polymer matrix at optimized concentrations. This composite structure with at least 60% metallic particles by weight provides both electronic conduction and reflective properties, resolving the inconsistency problem through proper material composition design.

Inventive Principle:
Principle #40Composite materials

2Reliability

If high concentration of metallic particles (around 60% by weight) is used in the composite material, then electronic conduction and reflective properties are achieved, but production costs increase and environmental impact worsens

Engineering Contradiction:
Improveelectronic conduction capabilityVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention replaces conventional mechanical mixing and heating methods with photochemical reduction using UV irradiation. This substitution allows metallic particles to be formed in situ within the polymer matrix at room temperature, reducing energy consumption and eliminating the need for harsh chemical reducing agents, thereby decreasing environmental impact while maintaining high metallic particle concentration for reliable electronic conduction.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention uses UV light to simultaneously initiate polymerization of the matrix and reduction of metal ions to metallic particles. The system serves itself by using the same energy source (UV irradiation) for both polymer formation and metal particle generation, eliminating the need for separate reducing agents and simplifying the process while reducing environmental harm.

Inventive Principle:
Principle #25Self-service

3Ease of manufacture

If conventional production methods are used, then manufacturing is achieved, but production costs are high and the process is not environmentally friendly

Engineering Contradiction:
Improvemanufacturing capabilityVSAvoidindustrial-scale production efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The invention merges polymerization and metal particle formation into a single photochemical process. UV irradiation simultaneously polymerizes the matrix material and reduces metal ions to metallic particles in situ. This merging of operations simplifies manufacturing, reduces process steps, and enables efficient industrial-scale production while maintaining ease of manufacture.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention replaces conventional thermal and mechanical processing with photochemical methods. UV irradiation initiates both polymerization and metal reduction at room temperature, eliminating the need for high-temperature processing, complex mixing equipment, and harsh chemical agents. This substitution simplifies manufacturing operations and improves productivity for industrial-scale production.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the production of a composite material with a metallic mirror surface and electronically conducting properties while reducing production costs and environmental impact, suitable for industrial-scale manufacturing.

Implementation Method 1

coupling photopolymerizing kinetics with photo-reducing kinetics

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

coupling photopolymerizing kinetics with photo-reducing kinetics

Methodology Applied
Scientific EffectPhoto-reduction: Photopolymerisation

Data Source

PatentUS10808138B2Metal-polymer composite material
Publication Date: 2020.10.20 CENT NAT DE LA RECH SCI (C N R S)
  • US10808138B2 patent drawing
  • US10808138B2 patent drawing
  • US10808138B2 patent drawing

AI summary

The present invention relates to composite material comprising a matrix and a metallic layer located at at least one surface of said composite material, said matrix comprising at least one polymer and a first population of particles of at least one electronically conducting metal, said layer comprising a second population of particles of at least one electronically conducting metal, a method for preparing such composite material and applications thereof.