Metal Powder Nanoparticle Adhesion for Additive Manufacturing

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Solution Overview

Problem

In layered manufacturing processes using metal powders, the formation of heterogeneous structures within three-dimensional shaped articles due to factors beyond energy beam irradiation, such as powder material properties, leads to defects and voids, which are difficult to suppress, affecting the homogeneity and quality of the final product.

Innovation Solution

A metal powder material comprising metal particles with a specific diameter range and nanoparticles adhered or mixed with them, where the nanoparticles reduce attractive forces between particles, enhance fluidity, and improve packing density, thereby stabilizing the powder bed and reducing defects during the manufacturing process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional metal powder is used in layered manufacturing, then the manufacturing process can be conducted, but heterogeneous structures and defects form in the three-dimensional shaped article

Engineering Contradiction:
Improvehomogeneity of three-dimensional shaped articleVSAvoiddefects and voids in shaped article
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

Nanoparticles are introduced as intermediary substances between metal particles to modify interparticle interactions. The nanoparticles reduce attractive forces between metal particles, preventing agglomeration and ensuring homogeneous distribution during powder bed formation and sintering processes, thereby eliminating defects and voids in the final shaped article

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the physical and chemical parameters of the powder material system by controlling particle diameter (10-100 μm), circularity (0.90 or more), and nanoparticle content (0.01-10 mass%). These parameter optimizations ensure smooth powder flow, stable powder bed formation, and homogeneous sintering, preventing heterogeneous structure formation

Inventive Principle:
Principle #35Parameter changes

2Productivity

If powder material is supplied to form a powder bed, then the layered manufacturing process can proceed, but powder material may not be uniformly spread leading to heterogeneous structure

Engineering Contradiction:
Improvesmooth supply of powder materialVSAvoiduniformity of powder bed
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The metal particles are engineered with specific parameters: diameter of 10-100 μm for optimal flow characteristics, and circularity of 0.90 or more for smooth movement. These parameter changes enable the powder to be uniformly spread across the build plate without clumping, ensuring homogeneous powder bed formation for high-precision manufacturing

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If metal particles are supplied through a nozzle in powder deposition method, then three-dimensional shaped article can be formed, but nozzle clogging occurs

Engineering Contradiction:
Improveformation of three-dimensional shaped articleVSAvoidsmooth powder supply without clogging
Core Design Contradiction:
Ease of manufactureVSEase of operation

Solution Approach 1:

The metal particles are designed with diameter of 10-100 μm and high circularity (0.90 or more), which optimizes their flow properties. These parameter changes prevent particle agglomeration and ensure smooth flow through the nozzle during powder deposition, eliminating clogging issues while maintaining ease of manufacturing three-dimensional shaped articles

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If powder material is packed in lower density, then handling is easier, but solidification shrinkage increases during energy beam irradiation

Engineering Contradiction:
Improvehandling of powder materialVSAvoidsolidification shrinkage of shaped article
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

Nanoparticles serve as intermediary agents that reduce attractive forces between metal particles, enabling the powder to maintain high packing density without excessive agglomeration. This allows the powder to be densely packed in the powder bed, minimizing void spaces and reducing solidification shrinkage during energy beam irradiation while remaining easy to handle

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The metal powder material ensures stable and homogeneous supply of powder, reduces clogging in nozzles, and enhances the quality of three-dimensional shaped articles by minimizing solidification shrinkage and defects, leading to improved fluidity and packing density, resulting in high-quality products.

Implementation Method 1

the nanoparticles are adhered to or mixed with the metal particles... reduce attractive forces between particles

Methodology Applied
Scientific EffectVan der Waals force: Van der Waals Force

Implementation Method 2

energy beam such as laser beam or electron beam is irradiated on a predetermined position of the powder bed... the powder material of the region having received the irradiation solidifies through melting and resolidification

Methodology Applied
Scientific EffectLaser beam irradiation: Laser

Implementation Method 3

energy beam such as laser beam or electron beam is irradiated on a predetermined position of the powder bed

Methodology Applied
Scientific EffectElectron beam irradiation: Electron Beam

Implementation Method 4

the powder material of the region having received the irradiation solidifies through melting and resolidification

Methodology Applied
Scientific EffectMelting and resolidification: Melting

Data Source

PatentUS11154929B2Metal powder material
Publication Date: 2021.10.26 DAIDO STEEL CO LTD
  • US11154929B2 patent drawing
  • US11154929B2 patent drawing
  • US11154929B2 patent drawing

AI summary

The present invention relates to a metal powder material containing: metal particles having a particle diameter d10 of 10 μm or more and 100 μm or less; and nanoparticles containing a metal or a metal compound, in which the particle diameter d10 is a particle diameter at which an under-sieve cumulative fraction in a mass base distribution of particle diameter reaches 10%, and the nanoparticles are adhered to or mixed with the metal particles.