Metal Refining Filtration Aids for Faster Battery Metal Recovery

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Solution Overview

Problem

The high cost and scarcity of cobalt, nickel, manganese, and lithium in rechargeable lithium batteries necessitate efficient recycling methods to recover these valuable metals while improving filterability for refining processes.

Innovation Solution

A method involving the use of filtration aids such as silicon dioxide, aluminium oxide, or calcium hydroxide to enhance the filterability of metal refining processes by forming precipitates, allowing for the separation of metals and impurities through controlled pH adjustments and filtration techniques.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional filtration methods are used to separate metals from impurities, then the separation process can be performed, but the filtration rate is slow and filterability is poor

Engineering Contradiction:
Improvefiltration rateVSAvoidfilterability
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent introduces a filtration aid as an intermediary substance that mediates between the precipitate and the filtration system. The filtration aid forms a porous matrix that traps impurities while allowing metal-containing solution to pass through, significantly improving both filtration rate and filterability without requiring complex equipment modifications

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical and chemical parameters of the filtration system by adding filtration aids that alter the pore structure, surface area, and filtration characteristics of the medium. This transforms the filtration process from a slow, clogging-prone operation to a high-rate process with sustained filterability

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If filtration aids are added to improve filterability, then filtration rate increases, but the process complexity increases

Engineering Contradiction:
ImprovefilterabilityVSAvoidprocess complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent employs inexpensive, readily available filtration aids (such as diatomaceous earth, cellulose, or synthetic polymers) that can be easily added and discarded after use. These disposable filtration aids simplify the overall process by eliminating the need for complex, expensive, or difficult-to-maintain filtration equipment

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent modifies the chemical composition parameters of the filtration system by incorporating filtration aids with specific properties (porosity, surface charge, particle size) that enhance filterability. These parameter changes are achieved through simple mixing operations rather than complex process equipment

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method significantly improves filtration rates and purity of recovered metals, enabling efficient recycling and reuse in the production of positive electrode active materials for lithium batteries.

Implementation Method 1

adding a filtration aid to the acid solution to make a precipitation reaction solution

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 2

controlled pH adjustments and filtration techniques

Methodology Applied
Scientific EffectpH adjustment:

Implementation Method 3

filtering the precipitation reaction solution to separate a liquid including the metal and a solid including the impurity and the filtration aid

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Data Source

PatentEP4609932A1Method of refining metal and method of fabricating positive electrode active material using the same
Publication Date: 2025.09.03 SAMSUNG SDI CO LTD
  • EP4609932A1 patent drawingFigure 1
  • EP4609932A1 patent drawingFigure 2
  • EP4609932A1 patent drawingFigure 3A~3C

AI summary

Methods of refining metals and methods of manufacturing positive electrode active materials are disclosed. The methods of refining metals comprise preparing an acid solution that includes an impurity and metal, adding a filtration aid to the acid solution to make a precipitation reaction solution, and filtering the precipitation reaction solution to separate a liquid including the metal and a solid including the impurity and the filtration aid. The filtration aid includes one or more of silicon dioxide (SiO2), aluminium oxide (Al2O3), calcium hydroxide (Ca(OH)2).