Metal Sidewall Spacers for Sub-20 Nm EUV Patterning

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Solution Overview

Problem

Conventional extreme ultraviolet (EUV) lithography scanners face resolution limits in printing critical dimensions below 20 nm for isolated structure patterns such as contacts and holes for vias, and Metal Organic Resists (MOR) and Chemically Amplified Resists (CAR) counterparts suffer from similar EUV resolution limitations.

Innovation Solution

A method involving forming a patterned resist with a first metal, partially exposing it, and creating a liner on the sidewalls using a second metal, followed by etching to form spacers, which allows for reducing critical dimensions below 20 nm by employing materials like Sn, In, Sb, Ti, Al, Zn, Hf, and Zr, with similar or identical etch rates to the resist.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional EUV lithography scanners are used, then the manufacturing process is simple, but the critical dimension resolution is limited to about 20 nm for isolated structures

Engineering Contradiction:
Improvecritical dimension resolutionVSAvoidpatterning process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patterning process is divided into multiple steps: forming initial patterned resist features, depositing a liner material on sidewalls, and using the liner as a template for final pattern formation. This segmentation allows each step to be optimized independently, achieving sub-20 nm resolution that cannot be obtained through single-step lithography

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The liner is formed on the sidewalls of the patterned resist features before the final pattern transfer. This preliminary action creates a template structure that defines the final critical dimensions, enabling precise control of feature sizes below 20 nm that would be unattainable with conventional direct lithography

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If thinner photoresist layers are used to achieve smaller critical dimensions, then the pattern transfer becomes easier with less defectivity, but the EUV resolution limitation remains at about 20 nm

Engineering Contradiction:
Improvecritical dimensionVSAvoidEUV resolution capability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The liner material acts as an intermediary between the patterned resist and the final pattern transfer. The liner is deposited on the sidewalls of the resist features and serves as a template that defines the final critical dimensions. This intermediary structure enables sub-20 nm resolution by decoupling the lithography step from the final pattern definition, allowing the resist thickness to be optimized for etch resistance while the liner thickness controls the final CD

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables efficient formation of patterns with critical dimensions less than 20 nm, improving feature uniformity, reducing defects, and lowering costs through the use of spacers formed directly after lithography, with enhanced throughput and low roughness.

Implementation Method 1

partially exposing the substrate to radiation through a mask. Accordingly, exposed resist portions and unexposed resist portions are formed

Methodology Applied
Scientific EffectPhotochemical reaction: Photopolymerisation

Implementation Method 2

forming a liner on the sidewalls. The liner comprises a second metal

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 3

the step of forming the liner is further followed by etching the liner. Thus, the liner is removed from the patterned features and the bottom portions of the recesses, and forming spacers on the sidewalls

Methodology Applied
Scientific EffectEtching:

Data Source

PatentUS12469703B2Methods for forming spacers and related structures
Publication Date: 2025.11.11 ASM IP HLDG BV
  • US12469703B2 patent drawing
  • US12469703B2 patent drawing
  • US12469703B2 patent drawing

AI summary

Methods for patterning and forming structures, as well as related structures and systems are disclosed. The methods comprise forming a liner on sidewalls of a patterned resist. The patterned resist comprises a first metal, and the liner comprises a second metal.