Metal-Substrate Electrochemical Element for Thin SOFC Support

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Solution Overview

Problem

Conventional solid oxide fuel cells using ceramic support substrates face issues with high material and processing costs due to the need for thick, expensive, and brittle substrates, which also complicate the arrangement of multiple power generating bodies and increase size and weight.

Innovation Solution

A metal substrate with gas flow allowing regions is used, featuring an electrode layer, electrolyte layer, and counter electrode layer, where the electrolyte layer is positioned between the electrode and counter electrode, and a metal oxide film is applied to prevent component dispersion and vaporization, enhancing strength, reliability, and reducing costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a ceramic support substrate is used to provide strength, then the strength is improved, but the material cost and processing cost increase, and the size and weight increase

Engineering Contradiction:
Improvesubstrate strengthVSAvoidmaterial cost and processing cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The invention changes the material parameter from ceramic to metal, fundamentally altering the substrate's properties. This enables thinning the substrate while maintaining strength, reduces material cost, and simplifies processing. The metal substrate with thickness of 0.03 to 0.5 mm provides sufficient strength without the cost and weight penalties of ceramic substrates requiring several millimeters thickness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite structure by forming a metal oxide film on the metal substrate surface. This composite approach combines the high strength and formability of metal with the oxidation resistance and stability of metal oxide, achieving both mechanical performance and chemical stability without using expensive ceramic materials.

Inventive Principle:
Principle #40Composite materials

2Strength

If a ceramic support substrate is used, then the strength is improved, but the device size and weight increase

Engineering Contradiction:
Improvesubstrate strengthVSAvoidsubstrate weight
Core Design Contradiction:
StrengthVSWeight of stationary object

Solution Approach 1:

Changing from ceramic to metal substrate material enables significant weight reduction. The metal substrate can be made much thinner (0.03 to 0.5 mm) while maintaining adequate strength, compared to ceramic substrates that require several millimeters thickness. This parameter change directly reduces both substrate weight and overall device weight.

Inventive Principle:
Principle #35Parameter changes

3Strength

If a ceramic support substrate is used, then the strength is improved, but the manufacturing precision and ease of arranging multiple power generating bodies deteriorate

Engineering Contradiction:
Improvesubstrate strengthVSAvoidfine processing capability
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The invention changes the substrate material from brittle ceramic to ductile metal, fundamentally improving manufacturability. The metal substrate can be precisely formed using conventional metal forming techniques, enabling accurate positioning of multiple power generating bodies. This material parameter change allows for fine processing and high manufacturing precision that is difficult to achieve with ceramic substrates.

Inventive Principle:
Principle #35Parameter changes

4Weight of stationary object

If the metal substrate is made thin to reduce size and weight, then the size and weight are reduced, but the strength deteriorates

Engineering Contradiction:
Improvesubstrate weightVSAvoidsubstrate strength
Core Design Contradiction:
Weight of stationary objectVSStrength

Solution Approach 1:

The invention applies a metal oxide film on the metal substrate surface, creating a composite structure. This composite approach maintains the lightweight advantage of thin metal substrate while the metal oxide film provides oxidation resistance and enhances surface stability. The combination allows thin substrate design without compromising overall structural integrity and chemical stability.

Inventive Principle:
Principle #40Composite materials

5Productivity

If multiple power generating bodies are arranged side-by-side on a single support substrate, then the performance is improved, but the processing cost and complexity increase when using ceramic substrates

Engineering Contradiction:
Improvepower generation performanceVSAvoidprocessing cost
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The invention changes the substrate material from ceramic to metal, which can be precisely formed using conventional metal forming techniques. This enables cost-effective mass production of substrates with multiple power generating bodies arranged side-by-side. The metal substrate's formability allows for integrated manufacturing of complex multi-body configurations without the high processing costs associated with ceramic fabrication.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a compact, high-performance electrochemical element with reduced material and processing costs, improved strength, and effective gas sealing, while preventing performance reductions due to component dispersion or vaporization.

Implementation Method 1

a metal oxide film is applied to prevent component dispersion and vaporization

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

the electrolyte layer is arranged at least between the electrode layer and the counter electrode layer

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Data Source

PatentUS11978937B2Electrochemical element, electrochemical module, electrochemical device, and energy system
Publication Date: 2024.05.07 OSAKA GAS CO LTD
  • US11978937B2 patent drawing
  • US11978937B2 patent drawing
  • US11978937B2 patent drawing

AI summary

An electrochemical element (Q) has a metal substrate (1) and multiple electrochemical reaction portions. The metal substrate (1) has gas flow allowing regions that allow the flowing of a gas between the upper side (4) and the lower side (5) of the metal substrate (1). The electrochemical reaction portions each have at least an electrode layer (A), an electrolyte layer (B), and a counter electrode layer (C), and are arranged on the upper side (4) of the metal substrate (1). The electrolyte layer (B) is arranged between the electrode layer (A) and the counter electrode layer (C), and the gas flowing through the gas flow allowing regions is supplied to the electrode layer (A).