Metal Sulfide Scale Dissolver Fluid for Oilfield Applications

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Solution Overview

Problem

Current methods for removing iron sulfide scale from oil and gas production systems are inefficient, with existing treatments often achieving only partial removal and risking metal corrosion and toxic byproduct production.

Innovation Solution

A treatment fluid comprising a base fluid and a metal sulfide dissolver, which includes a chelating agent, a boosting agent, a scaling agent, and a dispersing agent, is introduced into the wellbore to effectively dissolve and remove metal sulfide scale from production equipment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If chemical treatment with mineral acids is used to remove iron sulfide scale, then scale removal efficiency is improved, but metal corrosion and toxic byproduct production increase

Engineering Contradiction:
Improvescale removal efficiencyVSAvoidmetal corrosion and toxic byproduct production
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the treatment fluid by using organic acids (acetic, formic, maleic) with specific pH ranges (2-4) instead of mineral acids, and combines them with chelating agents to alter the chemical environment for safer and equally effective scale removal

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces chelating agents as intermediary substances that facilitate scale removal by complexing with metal ions, enabling the organic acid system to achieve mineral acid-level effectiveness without the harmful corrosion and toxic byproduct issues

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If organic acids with chelating agents are used to treat iron sulfide scale, then metal corrosion and toxic byproduct risks are reduced, but treatment effectiveness decreases and contact time increases

Engineering Contradiction:
Improvemetal corrosion and toxic byproduct risksVSAvoidtreatment effectiveness and contact time
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent merges organic acids with chelating agents in a single treatment fluid composition, combining the safety benefits of organic acids with the enhanced scale-dissolving capability of chelating agents to achieve both safety and effectiveness simultaneously

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent creates a composite chemical system combining organic acid components with chelating agent components, forming a synergistic treatment fluid that overcomes the limitations of either component alone and achieves high effectiveness with reduced contact time

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If current chemical treatments are used for iron sulfide scale, then partial scale removal is achieved (up to 60%), but complete scale removal is not attained and scale may reform

Engineering Contradiction:
Improvescale removal percentageVSAvoidcomplete scale removal and prevention of reformation
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent ensures continuous and complete scale dissolution through the synergistic action of organic acids and chelating agents, preventing scale reformation by maintaining a chemical environment that continuously binds metal ions and prevents precipitation

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent changes the chemical parameters of the treatment system by using specific organic acid-chelating agent combinations with optimized concentrations and pH ranges, creating conditions that enable complete scale removal rather than partial removal

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The treatment fluid achieves high efficiency in removing metal sulfide scale, with a 97% dissolution rate, compared to previous methods which typically achieved only up to 60% removal, while minimizing corrosion and toxic byproduct risks.

Implementation Method 1

a treatment fluid comprising a base fluid and a metal sulfide dissolver

Methodology Applied
Scientific EffectChelation: Chemical Bonding

Implementation Method 2

a dispersing agent

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS12275890B2Metal sulfide scale dissolver for oilfield application
Publication Date: 2025.04.15 STERLING SPECIALTY CHEM HLDG UK LTD
  • US12275890B2 patent drawing
  • US12275890B2 patent drawing

AI summary

A method may include providing a treatment fluid comprising a metal sulfide dissolver and a base fluid. The metal sulfide dissolver includes a chelating agent, a boosting agent, a scaling agent, and a dispersing agent. The treatment fluid is then injected to contact a metal sulfide scale, which dissolves at least partially. The treatment fluid may be injected into a wellbore as a standalone treatment or as an additive.