Metallic Nanocrystals in Nonvolatile Memory Fabrication

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Solution Overview

Problem

Conventional nonvolatile memory devices, such as SONOS memory devices, face issues with electric field concentration and defects affecting their physical characteristics, particularly due to the presence of substitution elements that can damage the tunnel oxide film and charge storage film, leading to operational problems during voltage applications.

Innovation Solution

A method of fabricating nonvolatile memory devices involving the formation of metallic nanocrystals between the charge storage film and the blocking insulation layer, where first and second metallic dots are formed through a substitution reaction, minimizing the diffusion of substitution elements and distributing the electric field uniformly, thereby reducing defect-induced issues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of stationary object

If substitution elements are used in the charge storage film, then the tunnel oxide film thickness can be reduced, but electric field concentration occurs at defects causing damage to films and operational problems

Engineering Contradiction:
Improvetunnel oxide film thicknessVSAvoidfilm integrity and operational stability
Core Design Contradiction:
Length of stationary objectVSReliability

Solution Approach 1:

Metallic nanocrystals are introduced as intermediary structures between the charge storage film and blocking insulation layer. These nanocrystals act as intermediate electrodes that redistribute the electric field, preventing concentration at defects while maintaining the thin tunnel oxide structure necessary for low operating voltage

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The electric field distribution parameter is changed from concentrated (at defects) to uniform (throughout the structure) by introducing metallic nanocrystals. This parameter change allows the thin tunnel oxide to withstand the electric field without damage, resolving the reliability issue

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If defects are present in the multi-layer film, then manufacturing is simplified, but electric field convergence at defects causes numerous operational problems

Engineering Contradiction:
Improvefabrication simplicityVSAvoiddevice operation reliability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

Instead of attempting to eliminate all defects (which would complicate manufacturing), the invention converts the harmful effect of defects into a beneficial one by introducing metallic nanocrystals that actively manage and redistribute the electric field around defect regions, transforming potential failure points into controlled field distribution zones

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively disperses the electric field and minimizes the impact of defects, enhancing the operational stability and reliability of the nonvolatile memory device by forming metallic nanocrystals that act as intermediate electrodes, ensuring a uniform electric field distribution and preventing substitution element diffusion.

Implementation Method 1

distributing the electric field uniformly, thereby reducing defect-induced issues

Methodology Applied
Scientific EffectElectric field distribution: Electric Field

Implementation Method 2

first and second metallic dots are formed through a substitution reaction, minimizing the diffusion of substitution elements

Methodology Applied
Scientific EffectSubstitution reaction: Chemical Bonding

Data Source

PatentUS7507627B2Method of fabricating nonvolatile memory device
Publication Date: 2009.03.24 SAMSUNG ELECTRONICS CO LTD
  • US7507627B2 patent drawing
  • US7507627B2 patent drawing
  • US7507627B2 patent drawing

AI summary

In one embodiment, a nonvolatile memory device can be fabricated by forming first metallic dots on a charge storage film using first source gas, forming substitution dots on the charge storage film on which the first metallic dots are formed and forming second metallic dots using a second source gas.