Multi-Layer Metallized Paper-Based Packaging for Oxygen and Moisture Barriers

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Solution Overview

Problem

Existing multilayer packaging materials face challenges in achieving sufficient barrier properties under mechanical stress and are difficult to recycle due to high cohesion and adhesion of plastic layers, leading to inefficient recycling processes and environmental impact.

Innovation Solution

A multi-layer metallized paper-based packaging material with a paper layer, pre-metallization and post-metallization coating layers, including ethylene acrylic acid copolymer and butylvinyl alcohol copolymer, which provides excellent barrier properties and facilitates easy recycling by reducing polymer adhesion to cellulose fibers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a thick plastic film layer is applied to provide barrier properties, then barrier performance is improved, but recyclability deteriorates due to high cohesion and adhesion preventing separation during recycling

Engineering Contradiction:
Improvebarrier performanceVSAvoidrecyclability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The plastic film is segmented into multiple thin layers with different functions: a barrier layer providing oxygen and moisture barrier properties, and a release layer with low adhesion to paper fibers. This segmentation allows the barrier function to be maintained while enabling easy separation during recycling, as the release layer detaches from the paper substrate in the pulping process.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A release layer acts as an intermediary between the barrier plastic layer and the paper substrate. This intermediate layer has low adhesion to paper fibers, facilitating easy separation during recycling while still allowing the barrier layer to provide its protective function. The release layer mediates between the need for strong barrier properties and the need for easy recyclability.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If extrusion or adhesive lamination is used to apply plastic layers, then barrier properties are improved, but the plastic layer becomes too cohesive and adherent to allow detachment during recycling

Engineering Contradiction:
Improvebarrier propertiesVSAvoidcohesion and adhesion strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

Different regions of the plastic coating have different adhesion properties: the barrier layer has strong cohesion to maintain integrity, while the release layer has deliberately low adhesion to paper fibers. This local differentiation of quality allows the structure to simultaneously provide strong barrier properties and easy separability during recycling.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The adhesion parameter of the plastic coating to paper is changed by introducing a release layer with specifically selected materials and thickness that provide low adhesion. This parameter change enables the plastic layer to detach easily during recycling while maintaining sufficient barrier properties through the barrier layer's inherent characteristics.

Inventive Principle:
Principle #35Parameter changes

3Strength

If multilayer structures with high polymer adhesion are used, then robustness and barrier properties are improved, but recycling efficiency deteriorates with low fiber yield and high energy consumption

Engineering Contradiction:
ImproverobustnessVSAvoidrecycling efficiency
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The release layer enables the extraction of the plastic barrier layer from the paper substrate during recycling. By designing the release layer with low adhesion properties, the plastic layers can be easily separated and removed from the paper fibers in the pulping process, significantly improving recycling efficiency and fiber yield while reducing energy consumption compared to strongly adherent multilayer structures.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The packaging material maintains excellent barrier properties against oxygen and moisture transfer even under mechanical stress, with high fiber content for easy recycling, achieving high fiber yield and reduced environmental impact.

Implementation Method 1

a metallized layer comprising a metal layer

Methodology Applied
Scientific EffectPhysical barrier:

Implementation Method 2

a pre metallization coating layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

at least one post metallization coating layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP4196636B1Multi-layer metallized paper-based packaging material
Publication Date: 2025.11.05 SOCIETE DES PRODUITS NESTLE SA
  • EP4196636B1 patent drawingFigure 1
  • EP4196636B1 patent drawingFigure 2

AI summary

The present invention relates generally to the field of multi-layer packaging material. In particular, the present invention relates to a multi-layer metallized paper-based packaging material comprising a paper layer, a pre metallization coating layer, a metallized layer, and at least one post metallization coating layer. The present invention further relates to the use of the multi-layer metallized paper-based packaging material in accordance with the present invention to package food and to a food package manufactured from the multi-layer metallized paper-based packaging material. In one embodiment of the present invention the multi-layer metallized paper-based packaging material can be recycled with other paper packaging materials.