Metallocene Polypropylene Nonwoven Fabric Production

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Solution Overview

Problem

Polypropylene nonwoven fabrics produced using metallocene catalysts face limitations in stretchability and water pressure resistance, while those produced with Ziegler-Natta catalysts have high xylene soluble content and TVOC, restricting their applications.

Innovation Solution

A method involving spinning metallocene polypropylene resin with specific molecular weight, molecular weight distribution, and xylene soluble content, followed by controlled cooling and bonding at specific temperatures to produce filaments with improved mechanical properties, stretchability, and water pressure resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If metallocene homopolypropylene resin is used, then uniform fibers with thin thickness can be produced, but stretchability and water pressure resistance are inferior

Engineering Contradiction:
Improvefiber uniformityVSAvoidstretchability
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent applies parameter changes by precisely controlling the molecular weight distribution (PDI) of metallocene homopolypropylene resin within 1.8-2.5, weight average molecular weight between 80,000-150,000, and melt index between 15-30 g/10min. These parameter optimizations enable the resin to produce uniform thin fibers while achieving improved stretchability (40-80% elongation) and water pressure resistance (150 mmH2O or more), resolving the contradiction between fiber uniformity and mechanical strength.

Inventive Principle:
Principle #35Parameter changes

2Strength

If Ziegler-Natta catalyst homopolypropylene resin is used, then strength and stretchability are excellent, but xylene soluble content and TVOC are high

Engineering Contradiction:
Improvemechanical strengthVSAvoidxylene soluble content
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent applies the extraction principle by removing the Ziegler-Natta catalyst system and exclusively using metallocene catalyst for polymerization. This eliminates the source of high xylene soluble content and TVOC emissions. The metallocene catalyst produces resin with PDI of 1.8-2.5 and xylene soluble content of 3% or less, while maintaining excellent mechanical strength through optimized molecular weight control (weight average molecular weight 80,000-150,000), thus extracting the harmful catalytic system while preserving desired properties.

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If metallocene homopolypropylene resin with narrow molecular weight distribution is used, then thin uniform fibers are produced, but water pressure resistance is inferior

Engineering Contradiction:
Improvefiber thickness uniformityVSAvoidwater pressure resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent resolves this contradiction through parameter changes by optimizing the molecular weight distribution width (PDI) to a specific range of 1.8-2.5, which is narrower than conventional resins but not excessively narrow. Combined with controlling weight average molecular weight at 80,000-150,000 and melt index at 15-30 g/10min, these parameter adjustments enable the production of uniform thin fibers that simultaneously achieve water pressure resistance of 150 mmH2O or more, overcoming the limitation of narrow distribution resins.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in polypropylene nonwoven fabrics with enhanced stretchability and water pressure resistance, exceeding 150 mmH2O, while maintaining excellent mechanical properties and reducing xylene soluble content.

Implementation Method 1

cooling the spun filaments at a temperature of 10 to 20° C.

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 2

bonding the cooled filaments together at 150 to 165° C. to form a nonwoven fabric

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

bonding the cooled filaments together at 150 to 165° C. to form a nonwoven fabric

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS11885044B2Method for producing polypropylene nonwoven fabric
Publication Date: 2024.01.30 LG CHEM LTD
  • US11885044B2 patent drawing
  • US11885044B2 patent drawing
  • US11885044B2 patent drawing

AI summary

The polypropylene nonwoven fabric produced by the method for producing a polypropylene nonwoven fabric according to the present invention has features that it has excellent stretchability and excellent water pressure resistance.