Metastable Hydrogen Carrier Temperature Control for Fuel Cells

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Solution Overview

Problem

Metastable hydrogen carriers in fuel cell systems face challenges in controlling hydrogen release to match demand, leading to potential over- or under-pressure issues, which can result in inefficient energy conversion and require costly high-pressure or low-temperature storage solutions.

Innovation Solution

A power control system that includes a metastable hydrogen carrier, a heater, and a controller to dynamically adjust the hydrogen release rate by controlling the temperature, with additional components like a purge valve and sensors to manage pressure and flow rate, ensuring stable energy delivery to fuel cells.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If metastable hydrogen carrier is used to store hydrogen, then hydrogen density is improved, but hydrogen release control becomes difficult

Engineering Contradiction:
Improvehydrogen densityVSAvoidhydrogen release control
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent changes the temperature parameter of the metastable hydrogen carrier to control hydrogen release rate. By adjusting temperature within a specific range, the system achieves both high hydrogen density storage and controllable release rates, resolving the contradiction between storage capacity and release control.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements a feedback control system that monitors hydrogen pressure and temperature, and adjusts heating power accordingly. This feedback mechanism ensures that hydrogen release from the metastable carrier matches fuel cell demand, preventing both over-pressurization and starvation conditions.

Inventive Principle:
Principle #23Feedback

2Productivity

If hydrogen release is left unchecked, then hydrogen release rate is improved, but pressure control deteriorates

Engineering Contradiction:
Improvehydrogen release rateVSAvoidhydrogen pressure control
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The control system continuously monitors hydrogen pressure and adjusts the heating rate accordingly. When pressure approaches upper limits, heating is reduced or stopped; when pressure is adequate, heating continues to maintain release rate. This feedback loop simultaneously manages both release rate and pressure control.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system dynamically adjusts the heating power and hydrogen release rate based on real-time fuel cell demand and pressure conditions. This dynamic control allows the system to optimize hydrogen release rate while maintaining pressure within safe operating limits.

Inventive Principle:
Principle #15Dynamics

3Quantity of substance

If high pressure storage is used, then hydrogen density is improved, but system cost and complexity increase

Engineering Contradiction:
Improvehydrogen densityVSAvoidstorage system complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent uses metastable hydrogen carriers that store hydrogen at ambient pressure but release it at controlled rates through temperature adjustment. This eliminates the need for high-pressure storage systems while maintaining effective hydrogen density, significantly reducing system complexity and cost.

Inventive Principle:
Principle #35Parameter changes

4Weight of moving object

If compact lightweight fuel cell system is designed, then portability is improved, but power control precision deteriorates

Engineering Contradiction:
Improvesystem weightVSAvoidpower control precision
Core Design Contradiction:
Weight of moving objectVSManufacturing precision

Solution Approach 1:

The compact system incorporates sensors and control algorithms that continuously monitor hydrogen pressure, temperature, and fuel cell performance. This feedback enables precise power control despite the reduced size and weight, maintaining control accuracy through intelligent algorithms rather than mechanical complexity.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively regulates hydrogen release to match energy demand, enhancing the efficiency and stability of fuel cell operations, particularly in compact and lightweight applications like UAVs, by optimizing temperature and composition-based hydrogen release rates.

Implementation Method 1

a heater coupled with the metastable hydrogen carrier

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

The controller operates the heater to control a rate of hydrogen release from the metastable hydrogen carrier

Methodology Applied
Scientific EffectThermal energy transfer: Conduction (thermal)

Implementation Method 3

Metastable hydrides can offer high volumetric and gravimetric hydrogen densities and rapid hydrogen release rates at low temperatures

Methodology Applied
Scientific EffectThermal decomposition: Thermolysis

Implementation Method 4

a fuel cell to generate an electrical power output

Methodology Applied
Scientific EffectFuel cell electrochemical conversion: Fuel Cell

Data Source

PatentUS11495810B1Power management system and method of operating the same
Publication Date: 2022.11.08 HRL LAB
  • US11495810B1 patent drawing
  • US11495810B1 patent drawing
  • US11495810B1 patent drawing

AI summary

According to an embodiment of the present disclosure, a power management system (e.g., a power management for a fuel cell or a fuel cell system) includes a fuel cell to generate an electrical power output; a metastable hydrogen carrier to supply hydrogen to the fuel cell; a heater coupled with the metastable hydrogen carrier; and a controller coupled to the heater to control a rate of hydrogen release from the metastable hydrogen carrier. A method of operating a fuel cell system includes controlling an electrical power input to a heater utilizing a controller; heating a metastable hydrogen carrier to a temperature by the heater and to generate hydrogen to feed a fuel cell. The heater is coupled to the controller, and the controller controls the electrical power input to the heater according to a relationship between a rate of hydrogen release and the temperature and a composition of the metastable hydrogen carrier.