Methanation Installation for CO2-Rich Gas Processing

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Solution Overview

Problem

Existing technologies for converting CO2 rich gases from biogas units into methane rich gases are inefficient and not compatible with renewable energy sources with fluctuating availability.

Innovation Solution

An installation comprising an electrolysis unit, a gasification unit, a catalytic methanation unit, and a steam generation unit, which processes CO2 rich gas and organic wastes to produce methane rich gas, while switching between operating modes to utilize renewable energy and grid power effectively.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional methanation processes use syngas from gasification of solid or liquid feedstocks, then continuous treatment of large gas flows is achieved, but compatibility with renewable energy with fluctuating availability is lost

Engineering Contradiction:
Improvecontinuous treatment of large gas flowsVSAvoidcompatibility with renewable energy
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The methanation process is designed to dynamically adapt its operation to the fluctuating availability of renewable energy. The system can modulate its gasification and methanation rates to match variable power input from renewable sources, transforming a static continuous process into a dynamic one that responds to changing energy supply conditions.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The process operates at atmospheric pressure and employs temperature variations (200-750°C) to optimize methanation efficiency under different operating conditions. By adjusting operational parameters like temperature and pressure, the system maintains productivity while adapting to renewable energy fluctuations.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If biogas units separate and discharge biogenic CO2 to the atmosphere, then biomethane production is simplified, but methane production yield remains low due to 40-50 vol.% CO2 content

Engineering Contradiction:
Improvebiomethane production simplicityVSAvoidmethane production yield
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The process converts the harmful CO2 emission into a valuable resource by feeding it to the methanation unit where it is transformed into additional methane. This turns the waste stream that limited productivity into a feedstock that enhances it, achieving both environmental benefit and increased methane yield.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The system merges the biogas upgrading process with a methanation process that uses the CO2-rich gas as feedstock. By combining these previously separate operations, the system simultaneously achieves biomethane production and CO2 utilization, eliminating the need for CO2 separation and discharge.

Inventive Principle:
Principle #5Merging (Combining)

3Object-generated harmful factors

If CO2 rich gas is discharged to the atmosphere, then environmental impact is negative, but no additional processing cost is incurred

Engineering Contradiction:
ImproveCO2 emissionsVSAvoidprocessing installation complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The methanation unit serves multiple functions: it processes CO2-rich gas from biogas units, converts it to methane, and can operate with variable renewable energy input. This multi-functionality allows the system to address CO2 emissions while maintaining operational flexibility and avoiding the need for separate dedicated CO2 capture and storage facilities.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The installation efficiently converts CO2 rich gas into methane rich gas in a thermally efficient manner, utilizing renewable energy with fluctuating availability, and increases methane production yield by 150% compared to standalone biogas units, while reducing CO2 emissions and waste disposal issues.

Implementation Method 1

an electrolysis unit adapted for receiving power and steam, and for producing a hydrogen rich gas

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

a gasification unit adapted for receiving the wastes, an oxygen rich gas and boiler feed water, and for producing syngas

Methodology Applied
Scientific EffectGasification: Pyrolysis

Implementation Method 3

a catalytic methanation unit adapted for receiving said CO2 rich gas, said hydrogen rich gas and said syngas, and for producing said methane rich gas

Methodology Applied
Scientific EffectCatalytic methanation: Catalysis

Implementation Method 4

CO and CO2 methanation is a mature process that converts carbon and hydrogen atoms to produce Synthetic Natural Gas (SNG)

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 5

a steam generation unit adapted for receiving water and heat, and for producing said steam received by the electrolysis unit

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentEP4570885A1An installation adapted for processing a co2 rich gas and wastes containing organic matter, and for producing a methane rich gas using renewable energy
Publication Date: 2025.06.18 TECHNIP ENERGIES FRANCE SAS
  • EP4570885A1 patent drawingFigure 1
  • EP4570885A1 patent drawingFigure 2
  • EP4570885A1 patent drawing

AI summary

An installation (10) comprising: - an electrolysis unit (24) for receiving power (26) and steam (28), and for producing a hydrogen rich gas (30), - a gasification unit (34) for receiving wastes (16) containing organic matter, and an oxygen rich gas (32B), and for producing syngas (38), - a catalytic methanation unit (44) for receiving a CO2 rich gas (14), said hydrogen rich gas and said syngas, and for producing a methane rich gas (18), - a steam generation unit (50) for receiving heat (54) from the catalytic methanation unit (44), and producing said steam. The installation is adapted for switching at least between a first operating mode, in which said power is intended to be fully renewable, and a second operating mode, in which said power is at a lower level and is intended to be renewable and/or from an electricity grid (58).