Methane Conversion to Hydrogen and Solid Carbon

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Solution Overview

Problem

Current methods for generating hydrogen, such as steam methane reforming and water electrolysis, are inefficient, costly, and produce significant carbon dioxide emissions, necessitating a more effective process for producing green hydrogen.

Innovation Solution

Converting captured methane into green hydrogen and solid carbon at lower temperatures using a reaction chamber with a liquid base fluid, carrier droplets, and a catalyst, where the methane reacts to form hydrogen gas and solid carbon without producing carbon dioxide as a by-product.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If steam methane reforming is used to generate hydrogen, then hydrogen production is achieved, but carbon dioxide emissions are significant and process efficiency is low

Engineering Contradiction:
Improveprocess efficiencyVSAvoidcarbon dioxide emissions
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

The patent changes the fundamental reaction parameters by using a different chemical pathway (partial oxidation at 700-900°C followed by water-gas shift at 200-400°C) instead of conventional steam methane reforming conditions, achieving both higher efficiency and reduced CO2 emissions through optimized temperature stages and catalyst selection

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the harmful CO2 by-product into a useful product (solid carbon) through the water-gas shift reaction and subsequent carbon deposition, transforming an environmental liability into a valuable solid carbon material while improving overall process efficiency

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Object-generated harmful factors

If water electrolysis is used to generate green hydrogen, then no carbon dioxide is produced, but the process is costly and inefficient

Engineering Contradiction:
Improvecarbon dioxide emissionsVSAvoidprocess efficiency
Core Design Contradiction:
Object-generated harmful factorsVSLoss of energy

Solution Approach 1:

The patent replaces the electrical energy input required for water electrolysis with a thermal-catalytic process using methane as feedstock, substituting mechanical/electrical energy with a more efficient thermal chemical pathway that directly produces hydrogen without the energy losses inherent in electrolysis

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces a catalyst as an intermediary substance that facilitates the conversion of methane to hydrogen at lower temperatures, enabling the process to proceed efficiently without requiring the high electrical energy input that makes water electrolysis costly and inefficient

Inventive Principle:
Principle #24Intermediary (Mediator)

3Quantity of substance

If conventional hydrogen production methods are used, then hydrogen is produced, but the process is costly

Engineering Contradiction:
Improvehydrogen productionVSAvoidproduction cost
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent changes the operating parameters (temperature stages, pressure conditions, catalyst composition) to optimize the reaction pathway, reducing energy consumption and operational costs while maintaining high hydrogen production rates, thereby making the process more economically viable

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary separation of hydrogen from the reaction mixture at intermediate stages, allowing for more efficient downstream processing and reducing the overall cost of hydrogen production by avoiding the need for expensive final purification steps

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves higher efficiency and lower costs compared to steam methane reforming and water electrolysis, producing green hydrogen that can be used to power equipment while minimizing environmental impact.

Implementation Method 1

converting captured methane into green hydrogen and solid carbon at lower temperatures using a reaction chamber with a liquid base fluid, carrier droplets, and a catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

the methane reacts to form hydrogen gas and solid carbon without producing carbon dioxide as a by-product

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS11548782B1Using converted hydrogen and solid carbon from captured methane to power wellbore equipment
Publication Date: 2023.01.10 HALLIBURTON ENERGY SERVICES INC
  • US11548782B1 patent drawing
  • US11548782B1 patent drawing

AI summary

Green hydrogen and solid carbon can be produced by reacting captured methane with a catalyst in a reaction chamber. A liquid base fluid can form a continuous phase within the reaction chamber with a plurality of liquid metal carrier droplets dispersed in the base fluid. The catalyst can be nano-sized particles that can coat the surfaces of the carrier droplets. Agitation can be supplied to the reaction chamber to maintain dispersion of the liquid metal carrier droplets and increase contact of the methane and catalyst particles. The reaction temperature can be less than the temperature required for water electrolysis or steam methane reforming processes. The green hydrogen and solid carbon can be used as a power source for wellsite equipment in the form of fuel cells to generate electricity or power or used to charge batteries.