Methane Purification Plant Using Hydrocarbon-Fueled CO2 Removal

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Solution Overview

Problem

Current methods for producing purified methane from natural gas and biogas are inefficient due to energy loss from pressure expansion and high operating costs associated with CO2 removal, particularly in small-scale liquefaction units, where heavy hydrocarbons and CO2 can cause equipment issues and require significant external energy for purification.

Innovation Solution

A plant and process that optimizes methane purification by using the pressure of the natural gas network and utilizing the energy from extracted heavy hydrocarbons to power CO2 removal, integrating a heavy hydrocarbon removal unit and a CO2 removal unit with a boiler to provide thermal energy for amine scrubbing, allowing for variable CO2 concentration adjustment in biogas purification to meet liquefaction standards.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stress or pressure

If natural gas is expanded from high-pressure network pressure to low-pressure biogas level, then pressure compatibility for processing is improved, but energy loss increases

Engineering Contradiction:
Improvepressure compatibilityVSAvoidenergy loss
Core Design Contradiction:
Stress or pressureVSLoss of energy

Solution Approach 1:

Instead of expanding natural gas from high pressure to low pressure, the invention inverts the approach by compressing biogas from low pressure to high pressure to match natural gas network pressure, thereby avoiding energy loss from expansion while achieving pressure compatibility for mixing and processing

Inventive Principle:
Principle #13The other way round (Inversion)

2Manufacturing precision

If biogas is purified to remove CO2 using conventional methods, then methane quality is improved, but operating costs increase

Engineering Contradiction:
Improvemethane qualityVSAvoidoperating costs
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The invention merges the CO2 removal process with the existing amine scrubbing infrastructure designed for natural gas, combining biogas purification with the same equipment and chemical system used for natural gas sweetening, thereby reducing operating costs while achieving required methane quality

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention changes the operating parameters of the amine scrubbing system to accommodate biogas characteristics, adjusting amine concentration, temperature, and pressure conditions to optimize CO2 removal efficiency for biogas while maintaining cost-effectiveness

Inventive Principle:
Principle #35Parameter changes

3Reliability

If heavy hydrocarbons are removed from natural gas, then equipment reliability is improved, but loss of valuable hydrocarbon substance occurs

Engineering Contradiction:
Improveequipment reliabilityVSAvoidhydrocarbon loss
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The invention recovers heavy hydrocarbons removed during natural gas processing by injecting them into the biogas stream, where they serve as fuel for the CO2 removal process, thereby preventing substance loss while maintaining equipment reliability through effective heavy hydrocarbon removal

Inventive Principle:
Principle #34Discarding and recovering

4Productivity

If biogas is compressed to high pressure for liquefaction, then liquefaction capability is improved, but energy consumption increases

Engineering Contradiction:
Improveliquefaction capabilityVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The invention merges the biogas compression function with the natural gas high-pressure network infrastructure, utilizing the existing high-pressure natural gas system to provide both process pressure and energy, thereby enabling liquefaction capability while reducing additional energy consumption requirements

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances energy efficiency by utilizing the natural gas network pressure and reduces operational costs by using the energy from heavy hydrocarbons for CO2 removal, optimizing the purification process for both natural gas and biogas to achieve high-quality methane production.

Implementation Method 1

a heavy hydrocarbon removal unit (3) comprising a first inlet (4) intended to be connected to a gas source (2) comprising natural gas, a first outlet (6) for gas purged of heavy hydrocarbons

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a boiler (11) for producing heat by combustion of heavy hydrocarbons

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 3

The CO2 removal unit comprises a first inlet (10) connected to the first outlet (6) of the heavy hydrocarbon removal unit (3), a first outlet (12) for gas of reduced CO2 content

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS20240352366A1Plant and process for production of purified methane
Publication Date: 2024.10.24 LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE
  • US20240352366A1 patent drawing

AI summary

A plant for production of purified methane from natural gas and biogas, having, arranged in series in a gas circuit, a heavy hydrocarbon removal unit and a CO2 removal unit. The plant includes a biogas purification unit having an inlet intended to be connected to a biogas source and a first purified biogas outlet connected to the first inlet of the CO2 removal unit, the biogas purification unit being configured to produce biogas or biomethane with a variable/defined CO2 concentration, anda boiler having a first inlet connected to the second outlet of the heavy hydrocarbon removal unit, the boiler being configured to produce a thermal power determined as a function of the amount of hydrocarbons removed and supplied by the heavy hydrocarbon removal unit, the boiler being fluidically connected to the CO2 removal unit to provide said unit with thermal energy produced for CO2 removal.