Methane Separation in Direct Iron Reduction Plant

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Solution Overview

Problem

Existing direct reduction processes for producing metallic iron face challenges in controlling the methane content in reducing gas, leading to inefficient temperature management in the reaction zone, excessive methane in exhaust gas, and difficulty in controlling carburization, which affects the quality and efficiency of the process.

Innovation Solution

A process that separates methane from synthesis gas entering the plant circuit, allowing precise control of methane levels in the reduction reaction zone and carburization zone, using pure methane as a cooling gas to reduce apparatus size and improve efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If methane is not separated from synthesis gas, then the reducing gas contains variable methane content, but this leads to inefficient temperature management in the reaction zone and excessive methane in exhaust gas

Engineering Contradiction:
Improvetemperature management in reaction zoneVSAvoidexcessive methane in exhaust gas
Core Design Contradiction:
TemperatureVSLoss of energy

Solution Approach 1:

The patent applies methane separation by extracting methane from synthesis gas using a processing device (e.g., cryogenic separation, membrane separation, or adsorption). This extraction allows precise control of methane content in the reducing gas fed to the reaction zone, optimizing temperature management while preventing excessive methane from reaching the exhaust gas stream.

Inventive Principle:
Principle #2Taking out (Extraction)

2Productivity

If methane content in reducing gas is not controlled, then the process is simpler, but this affects the quality and efficiency of the reduction process

Engineering Contradiction:
Improveefficiency of reduction processVSAvoidmethane separation and control system
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces a methane separation unit that extracts methane from synthesis gas before it enters the reducing gas system. This extraction device, combined with control valves and sensors, enables precise methane content control to optimize reduction efficiency, accepting the necessary increase in system complexity as a trade-off for improved productivity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent controls the methane content parameter in the reducing gas by adjusting the separation程度 and mixing ratios. By dynamically changing the methane concentration parameter, the system optimizes both temperature management and reduction efficiency, balancing productivity improvement with acceptable device complexity.

Inventive Principle:
Principle #35Parameter changes

3Volume of stationary object

If pure methane is used as cooling gas, then the apparatus size can be reduced, but this requires additional methane processing infrastructure

Engineering Contradiction:
Improveapparatus sizeVSAvoidmethane processing infrastructure
Core Design Contradiction:
Volume of stationary objectVSDevice complexity

Solution Approach 1:

The patent applies multi-functionality by using the separated pure methane for multiple purposes: (1) as cooling gas in the cooling zone to reduce apparatus size due to its high calorific value, (2) as a fuel source, and (3) potentially as a raw material for other processes. This multi-use approach justifies the methane processing infrastructure by providing multiple benefits from a single separation unit.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables better control over the reduction process, optimizing reaction kinetics and productivity, reducing re-oxidation of metallic iron, and lowering investment costs by using methane as a high-calorific cooling gas, thus improving the overall efficiency and quality of the direct reduction process.

Implementation Method 1

at stage i) at least a portion of the synthesis gas stream supplied by the external source is made to pass through a processing device to separate the methane from the synthesis gas, forming a fifth stream of pure methane and a sixth stream of reducing gas

Methodology Applied
Scientific EffectGas separation:

Implementation Method 2

heating of the reducing gas mixture in the heating means to a temperature of between 800° C. and 950° C.

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

a portion into the cooling zone... using methane as a high-calorific cooling gas

Methodology Applied
Scientific EffectHeat transfer: Convection

Implementation Method 4

direct reduction of iron ore using the appropriately processed synthesis gas obtained from a gasifier as the reducing gas

Methodology Applied
Scientific EffectReduction reaction: Reduction

Implementation Method 5

at least one carbon deposition zone... controlling the carburization process

Methodology Applied
Scientific EffectCarbon deposition: Deposition (physical)

Data Source

PatentUS7854786B2Reduction process and plant
Publication Date: 2010.12.21 DANIELI & C OFFICINE MECCANICHE SPA
  • US7854786B2 patent drawing
  • US7854786B2 patent drawing
  • US7854786B2 patent drawing

AI summary

Reduction process and relative plant for the production of metallic iron by means of the direct reduction of iron ore, in which a reduction shaft is connected to a source of reducing gas obtained from the gasification of coal. The process advantageously comprises a step in which a portion or all of the synthesis gas entering the plant circuit is processed to separate the methane from the rest of the components of said synthesis gas. The advantageous management of the extracted methane enables the entire reduction process to be optimized, making the efficiency of the process independent of the methane content in the original synthesis gas and making it possible to control the carbon content of the product more accurately and more easily.