Method and apparatus for cryogenic air separation

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Solution Overview

Problem

Existing cryogenic air separation methods cannot regulate liquid output to meet different yield requirements, as they lack the flexibility to adjust production according to actual needs.

Innovation Solution

The method involves compressing air to a higher pressure, partially cooling and expanding it through turboexpanders and boosters, and regulating the flow rates to vary the refrigeration input to the rectification column system, allowing for adjustment of liquid output yields by modifying the enthalpy drop and compression work.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a conventional cryogenic air separation method is used, then the system structure is simple, but the liquid output yield cannot be regulated to meet different requirements

Engineering Contradiction:
Improveliquid output yield regulationVSAvoidsystem structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The feed air stream is divided into multiple parts with different processing paths: one part is expanded in a turboexpander to provide refrigeration, another part is compressed in a booster compressor to high pressure, and a third part is expanded in a second turboexpander. This segmentation allows independent control of refrigeration input and liquid output yield without requiring complete system redesign.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system employs dynamic flow rate regulation of the air streams passing through the turboexpanders and booster compressor. By adjusting the flow rates of different air parts, the refrigeration input to the rectification column can be dynamically controlled, enabling flexible regulation of liquid output yield according to actual requirements.

Inventive Principle:
Principle #15Dynamics

2Productivity

If the refrigeration input is increased to increase liquid output yield, then the productivity improves, but the energy consumption increases

Engineering Contradiction:
Improveliquid output yieldVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The turboexpanders utilize the expansion of compressed air to generate refrigeration effect and drive the booster compressor, creating a self-sustaining system where the expansion work directly provides the refrigeration needed for liquid production. This reduces the need for external energy input while maintaining high productivity.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The system changes the pressure and temperature parameters of different air streams to optimize the refrigeration effect. By controlling the pressure ratios and flow rates through the turboexpanders and booster, the system achieves efficient refrigeration with minimized energy consumption across different productivity levels.

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If multiple compression stages are added to regulate flow rates, then the flow rate control precision improves, but the device complexity increases

Engineering Contradiction:
Improveflow rate control precisionVSAvoidnumber of compression stages
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The turboexpanders and booster compressor serve multiple functions simultaneously: they compress/expand air for pressure regulation, generate refrigeration effect for cooling, and control flow rates for yield regulation. This multi-functionality achieves precise flow rate control without adding dedicated compression stages, thereby avoiding increased device complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the apparatus to produce liquid output at varying yields by regulating the flow rates through turboexpanders and boosters, increasing or decreasing the refrigeration input, thus adapting to different requirements without the need for additional recompressors, reducing energy consumption and system complexity.

Implementation Method 1

a first part of the air of the third pressure is partially cooled in the main heat exchanger and expanded in a first turboexpander

Methodology Applied
Scientific EffectAdiabatic expansion: Adiabatic Cooling

Implementation Method 2

a main heat exchanger and a rectification column system which has a low-pressure column operating at a first pressure and a high-pressure column operating at a second pressure

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

further compressing a second part of the air at the third pressure in a first booster to form air at a fourth pressure

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 4

feeding all parts of the total feed air to the rectification column system at the first and/or the second pressure, at least some of the air being sent to the high pressure column, and obtaining a liquid stream from the rectification column system

Methodology Applied
Scientific EffectDistillation: Distillation

Data Source

PatentEP4151940A1Method and apparatus for cryogenic air separation
Publication Date: 2023.03.22 LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE
  • EP4151940A1 patent drawingFigure 1
  • EP4151940A1 patent drawing
  • EP4151940A1 patent drawing

AI summary

In a method for cryogenic air separation, part (b2) of the air (b) is compressed in warm booster (7), cooled in heat exchanger (2) and then divided in two, one part (c1) being compressed in a cold booster(9) driven by the Claude turbine (11) in which the other part (c2) of air (c) is expanded, another part of the feed air is not booster but is expanded in another Claude turbine (6) which drives the warm booster (7).