Coated Substrate Using MFC and CMC for Oxygen Barrier

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Solution Overview

Problem

Existing packaging materials face challenges in providing an efficient and environmentally friendly oxygen barrier, as current coating processes are energy-intensive and difficult to integrate into existing paper or board production lines, and often result in materials with high carbon footprints and recyclability issues.

Innovation Solution

A process for producing a coated substrate with cellulosic fibers using a coating composition of microfibrillated cellulose (MFC) and carboxymethyl cellulose (CMC) applied to a wet substrate, allowing for on-line integration with existing paper or board production processes, reducing energy consumption, and enhancing oxygen barrier properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If extrusion coating is used to provide oxygen barrier, then barrier performance is improved, but energy consumption increases due to multiple drying steps and integration difficulty

Engineering Contradiction:
Improveoxygen barrier performanceVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent combines the coating application and drying operations into a single integrated step by applying coating composition directly to the substrate on the paper machine, eliminating the need for separate drying sections that would be required in conventional extrusion coating processes

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The coating composition is applied to the substrate while it is still on the paper machine before final drying, allowing the coating to be deposited in advance and dried simultaneously with the substrate in the existing drying sections, rather than requiring post-production drying

Inventive Principle:
Principle #10Preliminary action

2Reliability

If aluminium foil is applied to provide barrier, then barrier performance is improved, but environmental impact increases due to carbon footprint and recyclability issues

Engineering Contradiction:
Improvebarrier performanceVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the material composition parameter from aluminium foil to organic-based coating materials (such as polyethylene, polypropylene, or starch-based coatings), transforming the barrier layer into an environmentally friendly alternative that is compatible with recyclable paper and board substrates

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses thin, disposable organic coating layers that can be applied in small amounts (0.1-10 µm thickness) to provide effective barriers, replacing the need for thicker, more persistent aluminium foil layers that are difficult to recycle

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If coating composition with major amount of colloidal polymer particles is used, then barrier performance is improved, but environmental friendliness decreases

Engineering Contradiction:
Improvebarrier performanceVSAvoidenvironmental friendliness
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses composite coating compositions that combine organic polymers (such as polyethylene, polypropylene, or starch derivatives) with cellulosic fibres, creating a biodegradable and environmentally friendly composite material that provides effective oxygen and moisture barriers

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs coating materials that are designed to be discarded with the packaging material in a single recycling stream, allowing the entire package (substrate plus coating) to be recycled together as paper or board, rather than requiring separation of persistent polymer coatings

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process enables the production of a high-quality, energy-efficient, and environmentally friendly packaging material with improved oxygen barrier properties, reducing the need for additional drying sections and equipment investments, while maintaining the quality of existing barrier methods.

Implementation Method 1

applying a coating composition to the first substrate in a total amount of over 10 g/m2 and less than 40 g/m2 The coating composition comprises microfibrillated cellulose (MFC) and carboxymethyl cellulose (CMC)

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP3234260B1Process for the production of a coated substrate comprising cellulosic fibres
Publication Date: 2021.02.03 STORA ENSO OYJ
  • EP3234260B1 patent drawingFigure 1~2
  • EP3234260B1 patent drawingFigure 3

AI summary

The present invention relates to process for the production of a coated substrate comprising cellulosic fibres, the process comprising the steps of: i) providing a first substrate comprising cellulosic fibres and having a dry content of less than 50%; ii) applying a coating composition to the first substrate in an amount of more than 5 g/m2,,calculated as dry weight of the coating composition, wherein the coating composition comprises: - microfibrillated cellulose (MFC), and - optionally a water retention agent selected from carboxymethyl cellulose (CMC), anionic polyacrylamide (A-PAM),sodium polyacrylates, polyacrylic acid derivatives, guar gum, alginate, MFC prepared from carboxymethylated fibers, MFC prepared from oxidized fibers, MFC preparedby CMC- functionalised fibers, and/or combinations thereof; and iii) mechanically dewatering the first substrate. The present process provides an energy efficient coating process which can be performed online.