Mg-Cu Alloy Supersaturated Solid Solution for Thin Component Bending

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

There is a demand for a copper alloy for electronic and electrical devices that can maintain excellent mechanical properties while being worked into thinner plate thicknesses or smaller wire diameters, as existing alloys face issues with defects and reduced bendability due to coarse inclusions and the reactivity of Mg, leading to cracking and manufacturing yield decreases.

Innovation Solution

A copper alloy with Mg content between 1.3% and 2.8% mass, along with controlled impurity levels of H, O, S, and C, is developed to suppress the formation of coarse intermetallic compounds, ensuring a supersaturated solid solution that improves strength and bendability, and includes additional elements like Sn, Zn, Al, and Ni to enhance characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If precipitation hardening is used to improve strength and proof strength, then strength is improved, but bendability significantly degrades

Engineering Contradiction:
Improveproof strengthVSAvoidbendability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The invention changes the chemical composition parameters by strictly controlling impurity elements (H≤10ppm, O≤100ppm, S≤50ppm, C≤10ppm) and Mg content (1.3-2.8mass%), which prevents coarse intermetallic compound formation while enabling supersaturated solid solution formation through heat treatment, thereby achieving both high strength and excellent bendability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention utilizes phase transition by forming a supersaturated solid solution through solution treatment followed by quenching, which suppresses intermetallic compound precipitation and maintains a homogeneous single-phase structure that provides both high strength and superior bendability

Inventive Principle:
Principle #36Phase transitions

2Strength

If Mg content is increased to improve strength, then strength is improved, but coarse intermetallic compounds are precipitated causing cracking during bending

Engineering Contradiction:
ImprovestrengthVSAvoidcracking resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention optimizes Mg content to 1.3-2.8mass% and strictly controls impurity elements (H≤10ppm, O≤100ppm, S≤50ppm, C≤10ppm) to prevent coarse intermetallic compound formation while maintaining high strength, achieving both strength improvement and cracking resistance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a controlled environment by minimizing reactive impurities (H, O, S, C) that would form coarse intermetallic compounds with Mg, effectively creating an inert chemical environment that prevents harmful phase formation while allowing Mg to strengthen the alloy through solid solution strengthening

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Length of moving object

If component thickness is reduced to meet size reduction demands, then device size is reduced, but manufacturing yield decreases due to defects and cracking

Engineering Contradiction:
Improvecomponent thicknessVSAvoidmanufacturing yield
Core Design Contradiction:
Length of moving objectVSProductivity

Solution Approach 1:

The invention changes the material composition parameters to eliminate coarse inclusions and intermetallic compounds through strict impurity control and optimized Mg content, creating a homogeneous supersaturated solid solution that enables defect-free plastic working of thin components with high manufacturing yield

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention achieves complete homogeneity by forming a supersaturated solid solution through solution treatment and quenching, which eliminates coarse intermetallic compounds and creates a uniform single-phase structure that prevents cracking and defects during plastic working of thin components

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The alloy achieves high 0.2% yield strength, improved conductivity, and excellent bendability, allowing for the formation of complex-shaped components without cracking, thereby enhancing manufacturing reliability and yield.

Implementation Method 1

a copper alloy which is used for components for electronic and electrical devices such as a terminal such as a connector, a relay, and a lead frame desirably has a high proof strength

Methodology Applied
Scientific EffectSupersaturated solid solution: Supersaturation

Implementation Method 2

in a case in which the content of Mg is 1.3% by mass or higher (3.3% by atom or higher), an intermetallic compound made up of Cu and Mg can be precipitated by performing a solution treatment and a precipitation treatment

Methodology Applied
Scientific EffectPrecipitation hardening: Precipitation Hardening

Data Source

PatentUS10294547B2Copper alloy for electronic and electrical equipment, plastically worked copper alloy material for electronic and electrical equipment, and component and terminal for electronic and electrical equipment
Publication Date: 2019.05.21 MITSUBISHI MATERIALS CORP
  • US10294547B2 patent drawing
  • US10294547B2 patent drawing
  • US10294547B2 patent drawing

AI summary

The present invention provides a copper alloy for electronic and electronic device which has excellent mechanical properties and is capable of suppressing generation of defects even in a case in which the copper alloy is worked to a thin plate thickness or a smaller wire diameter than in the related art, a plastically-worked copper alloy material, and a component and a terminal for electronic and electronic device. The copper alloy for electronic and electronic device of the present invention includes Mg in a range of 1.3 mass % to 2.8 mass % with a remainder substantially being Cu and inevitable impurities, in which a content of H is set to 10 mass ppm or lower, a content of O is set to 100 mass ppm or lower, a content of S is set to 50 mass ppm or lower, and a content of C is set to 10 mass ppm or lower.