Mg-Ge Oxide Epitaxy for Ultrawide-Bandgap Semiconductor Switching

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Solution Overview

Problem

Current semiconductor materials face limitations in achieving ultrawide bandgaps, direct bandgaps, and high dielectric breakdown voltages, which are essential for advanced electronic and optoelectronic devices, particularly for deep ultraviolet applications and high-power switching systems.

Innovation Solution

The development of magnesium germanium oxide (MgxGe1-xO2-x) epitaxial layers with specific crystal symmetries and doping strategies, allowing for the formation of high-quality single crystal structures with ultrawide bandgaps, direct bandgaps, and adjustable conductivity types, thereby enabling the creation of efficient semiconductor devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional semiconductor materials are used, then device manufacturing is easier, but ultrawide bandgap and direct bandgap properties cannot be achieved

Engineering Contradiction:
Improvebandgap propertiesVSAvoidmaterial synthesis
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs composite material strategy by creating MgxGe1-xO2-x compounds that combine magnesium oxide and germanium oxide in specific ratios. This composite approach enables achieving ultrawide bandgap (5.0-6.5 eV) and direct bandgap properties that neither parent compound can provide alone, while maintaining crystal structure compatibility with common substrates like MgO and LiF for practical device fabrication

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes by systematically varying the composition parameter x in MgxGe1-xO2-x to tune the bandgap energy from 5.0 eV to 6.5 eV. This continuous parameter adjustment allows optimization of optical and electrical properties for specific applications while maintaining manufacturability through controlled epitaxial growth processes

Inventive Principle:
Principle #35Parameter changes

2Reliability

If wide bandgap materials are used, then breakdown voltage tolerance improves, but on-state electrical losses increase

Engineering Contradiction:
Improvebreakdown voltage toleranceVSAvoidon-state electrical losses
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent applies parameter changes by adjusting the Mg content (x parameter) in MgxGe1-xO2-x to optimize the balance between breakdown voltage tolerance and on-state electrical losses. By controlling composition and doping levels, the material achieves both high voltage tolerance and reduced resistive losses, resolving the trade-off between these two critical performance parameters

Inventive Principle:
Principle #35Parameter changes

3Speed

If conventional transistors are used, then device complexity is lower, but switching speed is insufficient for high-frequency applications

Engineering Contradiction:
Improvetransistor switching speedVSAvoiddevice structure
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent employs parameter changes by utilizing the unique electrical properties of MgxGe1-xO2-x materials, including high electron mobility and controllable carrier concentration through doping. These material parameter optimizations enable faster switching speeds in transistor devices while managing the increased structural complexity through systematic material design rather than complex device architectures

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of MgxGe1-xO2-x materials in semiconductor devices results in enhanced electrical breakdown voltage tolerance, reduced on-state electrical losses, increased transistor switching speed, and improved overall switching efficiency, making them suitable for extreme UV applications and high-power electronic devices.

Implementation Method 1

an epitaxial layer of MgxGe1-xO2-x on the substrate

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 2

Materials are co-deposited onto the substrate to form the epitaxial layer of MgxGe1-xO2-x

Methodology Applied
Scientific EffectCo-deposition:

Implementation Method 3

additional elements are incorporated into the MgxGe1-xO2-x crystal to alter the electronic properties, such as the electrical conductivity type

Methodology Applied
Scientific EffectDoping: Dopants

Data Source

PatentUS12266697B2Ultrawide bandgap semiconductor devices including magnesium germanium oxides
Publication Date: 2025.04.01 SILANNA UV TECH PTE LTD
  • US12266697B2 patent drawing
  • US12266697B2 patent drawing
  • US12266697B2 patent drawing

AI summary

Various forms of MgxGe1-xO2-x are disclosed, where the MgxGe1-xO2-x are epitaxial layers formed on a substrate comprising a substantially single crystal substrate material. The epitaxial layer of MgxGe1-xO2-x has a crystal symmetry compatible with the substrate material. Semiconductor structures and devices comprising the epitaxial layer of MgxGe1-xO2-x are disclosed, along with methods of making the epitaxial layers and semiconductor structures and devices. Also disclosed is single crystal MgxGe1-xO2-x, with x having a value of 0≤x<1. The single crystal MgxGe1-xO2-x may comprise a dopant chosen from Ga, Al, Li+, N3+. The single crystal MgxGe1-xO2-x may comprise a p-type conductivity.