Magnesium-Group IV Oxide Epitaxy for Deep-UV and High-Voltage Semiconductors

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Solution Overview

Problem

Conventional semiconductor materials are technologically limiting for applications requiring wide bandgaps, such as short UV LEDs, high-efficiency power switching systems, and solar blind detectors, as they fail to achieve ultraviolet wavelengths shorter than 260 nm and do not provide sufficient electrical breakdown voltage tolerance or switching efficiency.

Innovation Solution

Development of magnesium-group IV oxide epitaxial layers, including magnesium germanium oxides with specific crystal symmetries and doping strategies, allowing for the formation of high-quality single crystal structures with direct bandgaps suitable for UV emission and high breakdown voltages, which can be grown on compatible substrates using techniques like molecular beam epitaxy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional semiconductor materials are used, then device fabrication is straightforward, but ultraviolet wavelengths shorter than 260 nm cannot be achieved and electrical breakdown voltage tolerance is insufficient

Engineering Contradiction:
Improveultraviolet wavelength precisionVSAvoidmaterial fabrication difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent employs composite material structures including AlGaN superlattices and MgO buffer layers combined with GaN active layers. These composite structures enable precise control of ultraviolet emission wavelengths below 260 nm while maintaining manufacturability through established epitaxial growth techniques on standardized substrates

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically varies compositional parameters (Al content in AlGaN, Mg content in MgO buffer layers) and structural parameters (layer thickness, superlattice period) to precisely control the bandgap and achieve specific ultraviolet wavelengths. This parameter optimization enables wavelength precision below 260 nm while keeping fabrication processes manageable

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If wide bandgap materials are adopted to achieve shorter UV wavelengths, then UV emission capability improves, but manufacturing complexity increases

Engineering Contradiction:
ImproveUV wavelength controlVSAvoidepitaxial structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent divides the semiconductor structure into segmented functional layers: MgO buffer layers for substrate preparation, AlGaN superlattice layers for wavelength control, and GaN active layers for light emission. This segmentation allows independent optimization of each layer's properties to achieve precise UV wavelength control below 260 nm while managing overall device complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces MgO buffer layers and AlGaN superlattice intermediary layers between the substrate and the GaN active layer. These intermediary structures mediate the transition from conventional substrates to the wide bandgap GaN material, enabling precise UV wavelength control while simplifying the overall manufacturing process by decoupling substrate requirements from active layer properties

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If high breakdown voltage tolerance is achieved through material selection, then electrical performance improves, but switching efficiency may be compromised

Engineering Contradiction:
Improveelectrical breakdown voltage toleranceVSAvoidswitching efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent optimizes the MgO buffer layer composition and thickness parameters to achieve high breakdown voltage tolerance. By carefully controlling the MgO layer properties and transitioning to GaN-based active layers with appropriate doping levels, the patent achieves both high voltage tolerance and efficient switching performance through coordinated parameter optimization across multiple layers

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The magnesium-group IV oxides enable efficient UV emission and detection in the deep ultraviolet range, enhance electrical breakdown voltage tolerance, and improve switching efficiency in power management systems, overcoming limitations of conventional materials.

Implementation Method 1

an epitaxial layer comprises single crystal Mga(Six(GeySn1-y)1-x)Ob

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 2

which can be grown on compatible substrates using techniques like molecular beam epitaxy

Methodology Applied
Scientific EffectMolecular beam epitaxy: Physical Vapour Deposition

Data Source

PatentUS20250212474A1Magnesium Group IV Oxides
Publication Date: 2025.06.26 SILANNA UV TECH PTE LTD
  • US20250212474A1 patent drawing
  • US20250212474A1 patent drawing
  • US20250212474A1 patent drawing

AI summary

Various forms of Mga(Six(GeySn1-y)1-x)Ob are disclosed. In some aspects, an epitaxial layer comprises single crystal Mga(Six(GeySn1-y)1-x)Ob, wherein 1.5≤a≤2.5, 3≤b≤5, 0≤x≤1, and 0≤y≤1; wherein the single crystal Mga(Six(GeySn1-y)1-x)Ob has a crystal symmetry compatible with a substrate or an underlying layer on which the single crystal Mga(Six(GeySn1-y)1-x)Ob is grown. In some aspects, a semiconductor structure includes an epitaxial layer comprising single crystal Mga(Six(GeySn1-y)1-x)Ob, wherein 1.5≤a≤2.5, 3≤b≤5, 0≤x≤1, and 0≤y≤1; The semiconductor structure also includes a substrate or an underlying layer on which the single crystal Mga(Six(GeySn1-y)1-x)Ob is grown; wherein the single crystal Mga(Six(GeySn1-y)1-x)Ob has a crystal symmetry compatible with the substrate or the underlying layer.