Chelating Agent and Amino Acid Cleaning Composition

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Solution Overview

Problem

Modern cleaning compositions face challenges in providing excellent cleaning performance, especially in automatic dishwashing formulations, where they struggle with spotting, filming, and fatty residue accumulation, while also needing to be environmentally friendly and effective in hard water conditions.

Innovation Solution

The use of a cleaning composition containing alkali metal salts of methyl glycine diacetic acid (MGDA) and citric acid, combined with glycine or alanine, in specific weight ratios, along with additional components like surfactants and bleaching agents, to enhance cleaning efficacy and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cleaning compositions are used, then cleaning performance is achieved, but fatty residues accumulate in filters and sieves

Engineering Contradiction:
Improvecleaning performanceVSAvoidfatty residue accumulation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful effect of fatty residues by using specific chelating agents (MGDA, GLDA, citric acid) in combination with amino acids (glycine, alanine) that transform the deposition problem into effective soil removal. The chelating agents bind metal ions that would otherwise promote fatty residue adhesion, while amino acids provide emulsifying and dispersing effects that prevent residue accumulation in filters.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention uses a composite system combining multiple chelating agents (MGDA, GLDA, citric acid) with amino acids (glycine, alanine) in specific weight ratios. This composite approach creates synergistic effects where the chelating agents address metal ion binding while amino acids provide additional cleaning and anti-deposition properties, effectively preventing fatty residue accumulation while maintaining cleaning performance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If cleaning compositions are designed for excellent cleaning performance, then spotting and filming are reduced, but environmental friendliness may be compromised

Engineering Contradiction:
Improvecleaning performanceVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters by using biodegradable chelating agents (MGDA, GLDA, citric acid) instead of traditional non-biodegradable alternatives like EDTA. These agents maintain effective metal ion binding capabilities for spotting and filming prevention while being environmentally friendly and readily biodegradable, thus resolving the contradiction between cleaning performance and environmental impact.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs readily biodegradable chelating agents that break down quickly in the environment, effectively treating them as short-living substances that perform their cleaning function and then decompose without persistent environmental harm. This approach maintains cleaning efficacy while minimizing long-term environmental impact.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If cleaning compositions work in hard water conditions, then cleaning effectiveness is maintained, but chelating agent stability may be reduced

Engineering Contradiction:
Improvecleaning effectiveness in hard waterVSAvoidchelating agent stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent creates a composite system where multiple chelating agents (MGDA, GLDA, citric acid) work together with amino acids (glycine, alanine). This combination provides enhanced stability in hard water conditions through synergistic metal ion binding, where the amino acids supplement the chelating agents' stability while maintaining effectiveness in calcium and magnesium presence.

Inventive Principle:
Principle #40Composite materials

4Object-affected harmful factors

If filters are cleaned frequently to remove fatty residues, then hygiene is improved, but productivity is reduced

Engineering Contradiction:
Improvehygiene qualityVSAvoidmachine operational efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent converts the harmful fatty residue deposition into a beneficial effect by using chelating agents and amino acids that actively prevent residue adhesion to filter surfaces. The chemical composition transforms the filter from a site of harmful accumulation to one that remains clean, reducing maintenance frequency while improving hygiene through the cleaning action of the composition itself.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves excellent cleaning properties, reduces fatty residue accumulation, and maintains effectiveness in hard water conditions, providing a more stable and environmentally friendly solution for automatic dishwashing.

Implementation Method 1

chelating agents selected from alkali metal salts of methyl glycine diacetic acid (MGDA) and of citric acid

Methodology Applied
Scientific EffectChelation:

Implementation Method 2

glycine serves as enzyme stabilizer

Methodology Applied
Scientific EffectEnzyme stabilization: Enzyme

Data Source

PatentEP3822335B1Cleaning compositions and their use
Publication Date: 2022.10.12 BASF SE
  • EP3822335B1 patent drawing
  • EP3822335B1 patent drawing
  • EP3822335B1 patent drawing

AI summary

The present invention is directed towards cleaning compositions containing (A) at least one chelating agent selected from alkali metal salts of methyl glycine diacetic acid (MGDA) and of glutamic acid diacetic acid (GLDA) and of citric acid, (B) an alkali metal salt of glycine or alanine, in a weight ratio of (A):(B) of from 10:1 to 1:10.