Micro Copper Bonding Pads With [111] Grain Orientation

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Solution Overview

Problem

Conventional tin contacts and copper bonding structures in micro-scale or nano-scale electronic devices compromise the mechanical characteristics and reliability of electrical connections, necessitating a better electrical connection structure and forming method.

Innovation Solution

The electrical connection employs [111]-oriented copper grains in bonding pads with a maximum width of 8 microns or less, formed using periodic reverse electroplating, where the length covered by [111]-oriented copper grains accounts for 60% or more of the interface width, enhancing mechanical strength and electrical performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional tin contacts and copper bonding structures are used in micro-scale or nano-scale electronic devices, then electrical connection can be achieved, but the mechanical characteristics and reliability of the electrical connection deteriorate

Engineering Contradiction:
Improvereliability of electrical connectionVSAvoidmechanical characteristic of bonding structure
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the crystallographic orientation parameter of copper grains from conventional random or other orientations to specifically [111]-oriented grains. This parameter change in grain orientation fundamentally alters the mechanical properties of the copper bonding pad, enabling it to maintain excellent mechanical strength and reliability even at micro-scale dimensions (≤8 microns) where conventional copper structures would fail.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by combining [111]-oriented copper grains with silicon dioxide, forming a heterojunction interface. This composite material approach leverages the complementary properties of copper (electrical conductivity) and silicon dioxide (mechanical support and insulation), resulting in a bonding structure that simultaneously achieves excellent electrical performance and mechanical characteristics.

Inventive Principle:
Principle #40Composite materials

2Length of moving object

If bonding pad size is reduced to micro-scale or nano-scale, then device miniaturization is achieved, but the quality and reliability of bonding deteriorates

Engineering Contradiction:
Improvesize of bonding padVSAvoidbonding quality
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

By changing the grain orientation parameter to [111], the patent enables copper bonding pads to maintain high reliability at reduced sizes. The [111]-oriented grains provide enhanced mechanical strength and stability that compensates for the reduced cross-sectional area, allowing bonding pads with maximum width ≤8 microns to achieve bonding quality comparable to or exceeding conventional larger structures.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality enhancement by creating a specific [111]-oriented grain structure within the bonding pad region, while other parts of the device may have different structures. This localized optimization of grain orientation in the bonding pad area provides targeted improvement in mechanical properties and bonding reliability without requiring changes to the entire device structure.

Inventive Principle:
Principle #3Local quality

3Strength

If [111]-oriented copper grains are used in bonding pads with maximum width of 8 microns or less, then mechanical strength and reliability are improved, but the complexity of forming such structured grains increases

Engineering Contradiction:
Improvemechanical strength of bonding padVSAvoidcomplexity of grain formation process
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent employs preliminary action by preparing the substrate and controlling nucleation conditions before copper deposition, so that [111]-oriented grains are formed during the electroplating process itself. This preliminary preparation of surface conditions and deposition parameters enables the formation of desired grain structure during manufacturing, avoiding the need for complex post-processing steps to induce grain orientation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces mechanical grain alignment methods (such as rolling or forging) with an electrochemical approach using periodic reverse electroplating. This substitution of the grain formation mechanism from mechanical to electrochemical processes enables precise control of grain orientation through electrical parameters rather than mechanical forces, simplifying the overall manufacturing process for micro-scale bonding pads.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Manufacturing precision

If periodic reverse electroplating is used to form bonding pads with controlled grain orientation, then manufacturing precision of grain structure is improved, but the manufacturing process complexity increases

Engineering Contradiction:
Improveprecision of grain orientation controlVSAvoidease of electroplating process
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent applies periodic action through reverse electroplating, where the electroplating process is cycled between deposition and dissolution phases. This periodic cycling allows precise control of grain nucleation and growth by repeatedly forming and refining the grain structure, achieving high manufacturing precision of [111]-oriented grains. The periodic nature of the process enables fine-tuning of grain orientation through parameter adjustment during each cycle.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves the mechanical strength and reliability of micro-scale or nano-scale electrical connections by reducing thermal budget and promoting heterojunction of copper/silicon dioxide at low temperatures, while minimizing the impact of sidewall effects on grain orientation.

Implementation Method 1

forming a first bonding pad by using a first periodic reverse electroplating, in which the first bonding pad includes a plurality of [111]-oriented copper grains

Methodology Applied
Scientific EffectElectroplating: Electroplating

Implementation Method 2

providing a pulse current to the first driving substrate, in which the pulse current comprises a plurality of pulse periods each comprising a forward current and a backward current

Methodology Applied
Scientific EffectElectrochemical reduction: Electrolysis

Data Source

PatentUS20240234351A9Electrical connection and forming method thereof
Publication Date: 2024.07.11 NAT YANG MING CHIAO TUNG UNIV
  • US20240234351A9 patent drawing
  • US20240234351A9 patent drawing
  • US20240234351A9 patent drawing

AI summary

An electrical connection includes a first driving substrate, a first adhesive layer, a first bonding pad a first bonding pad and a second bonding pad. The first driving substrate includes a first substrate and a first dielectric layer on the first substrate. The first adhesive layer is at a sidewall of the first dielectric layer of the first driving substrate. The first bonding pad is on the first substrate of the first driving substrate and in contact with the first adhesive layer, and the first bonding pad includes a plurality of grains, the grains are connected with each other, the grains include [111]-oriented copper grains, and a maximum width of the first bonding pad is equal to or less than 8 microns. The second bonding pad is on the first bonding pad.