Micro-irrigation Plugging Prevention via Organic Acid Complexation

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Solution Overview

Problem

Micro-irrigation systems are prone to plugging due to the formation of insoluble salts and particulates when phosphate fertilizers are added to irrigation water, especially in systems using impure water sources, leading to uneven water and nutrient distribution and potential system shutdowns.

Innovation Solution

A synergistic combination of a water-soluble organic acid and a water-soluble organophosphonate is added to the irrigation water before or with the phosphate fertilizer, stabilizing the water-fertilizer matrix and preventing precipitate formation, thus preventing plugging in micro-irrigation systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If phosphate fertilizers are added to irrigation water in micro-irrigation systems, then crop nutrient supply is improved, but plugging of emitters occurs due to insoluble salt formation

Engineering Contradiction:
Improvephosphate fertilizer supplyVSAvoidsystem plugging
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent introduces organic acids (such as citric acid, acetic acid, or propionic acid) as intermediary substances that chemically complex with calcium ions in the irrigation water. This mediation prevents calcium phosphate precipitation by keeping phosphate ions in solution through stable complex formation, thereby allowing phosphate fertilizer application without emitter plugging.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameters of the irrigation water by adjusting pH levels and adding organic acid modifiers. By controlling the chemical environment (pH, complexing agent concentration), the solubility of phosphate salts is maintained, preventing precipitation while delivering adequate phosphate nutrition to crops.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If irrigation water contains dissolved minerals, then water availability is improved, but precipitate formation increases when phosphate fertilizer is added

Engineering Contradiction:
Improvewater availabilityVSAvoidprecipitate formation
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

Organic acids serve as intermediary substances that bind to calcium and other metal ions present in dissolved form in irrigation water. This complexation prevents these ions from reacting with phosphate to form insoluble precipitates, allowing the use of mineral-containing irrigation water without precipitate problems.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If emitters have tiny orifices for precise water delivery, then water distribution precision is improved, but sensitivity to particulate plugging increases

Engineering Contradiction:
Improvewater delivery precisionVSAvoidparticulate fouling
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary anti-action by adding organic acid modifiers to the irrigation water before it reaches the emitters. This pre-treatment prevents particulate formation and dissolution of potential cloggers upstream, protecting the precise emitter orifices from fouling before the water enters the critical delivery components.

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents precipitation and plugging in micro-irrigation systems, ensuring stable and prolonged delivery of fertilized water, even with hard and alkaline water sources, by maintaining the system's functionality and uniform nutrient distribution.

Implementation Method 1

The present invention employs cost-effective additives that act synergistically in the stabilization of the agricultural irrigation water and fertilizer matrix

Methodology Applied
Scientific EffectComplexation:

Implementation Method 2

Phosphate fertilizers can form insoluble salts and/or cause particulate formation when added to the irrigation water

Methodology Applied
Scientific EffectSolubility enhancement:

Data Source

PatentUS9439345B1Method and composition for preventing plugging in micro-irrigation systems
Publication Date: 2016.09.13 DEERPOINT GROUP LLC
  • US9439345B1 patent drawing
  • US9439345B1 patent drawing
  • US9439345B1 patent drawing

AI summary

An agricultural micro-fertigation water includes a phosphate fertilizer, a water-soluble organic acid and a water-soluble organophosphonate, and is prepared by a method wherein the phosphate fertilizer is added to the irrigation water as a chaser to (addition with or after components of) the combination of a water-soluble organic acid and water-soluble organophosphonate to fully prevent precipitation and thus prevent plugging of a micro-irrigation system despite the addition of phosphate fertilizer in water having a precipitation factor of from 125 to 1,000 ppm, wherein said precipitation factor is a combined level of total alkalinity (as CaCO3) in ppm and total hardness (as CaCO3) in ppm.