Synergistic Microbicidal Composition Surfactant Oxazolidine

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Solution Overview

Problem

Current microbicidal compositions lack synergistic activity against various microorganism strains, requiring higher levels of individual microbicides, which is economically and environmentally undesirable.

Innovation Solution

A synergistic microbicidal composition comprising a nonionic surfactant and cis-1-(3-chloroallyl)-3,5,7-triaza-1-azoniaadamantane chloride, 4,4-dimethyloxazolidine, or tris(hydroxymethyl)nitromethane, with specific weight ratios that provide effective microorganism control at lower microbicide levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If higher levels of individual microbicides are used, then effective control of microorganisms is achieved, but economic and environmental costs increase

Engineering Contradiction:
Improvemicroorganism control effectivenessVSAvoidmicrobicide concentration
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent combines a quaternary ammonium compound (CTAC) with a nonionic surfactant (specifically IGEPAL CO-520 or TERGITOL L61) to create a synergistic microbicidal composition. This combination achieves enhanced microbial control effectiveness while reducing the required concentration of individual microbicides, thereby resolving the contradiction between reliability and quantity of substance.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a composite microbicidal system by formulating specific weight ratios of CTAC (0.01-5% w/w) with nonionic surfactants (0.1-10% w/w). This composite approach leverages the complementary properties of both components to achieve superior microorganism control at lower overall concentrations, addressing both economic and environmental concerns.

Inventive Principle:
Principle #40Composite materials

2Reliability

If combinations of microbicides with synergistic activity are developed, then effective control is achieved at lower levels, but formulation complexity increases

Engineering Contradiction:
Improvemicroorganism control effectivenessVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent optimizes specific parameters including the weight ratio of CTAC to nonionic surfactant (0.01:1 to 5:1), the molecular structure of the nonionic surfactant (ethylene oxide-propylene oxide block copolymers with specific HLB values), and concentration ranges. These parameter optimizations enable synergistic activity while maintaining relatively simple formulation procedures.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS9986739B2Microbicidal composition
Publication Date: 2018.06.05 NUTRITION & BIOSCIENCES USA 2 LLC

AI summary

A synergistic microbicidal composition having two components. The first component is a nonionic surfactant with structure: R1O(CH2CH(CH3)O)5(CH2CH2O)9H, where R1 is a C8 alkyl group. The second component is 4,4-dimethyloxazolidine. The weight ratio of the nonionic surfactant to 4,4-dimethyloxazolidine is from 1:0.0286 to 1:0.1143 or 1:0.32 to 1:0.9143.