Microcapsule Adhesive Structure for On-Demand Low-Pressure Bonding

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Solution Overview

Problem

Pressure-sensitive adhesives (PSAs) with microcapsules embedded within the adhesive layer require high pressures to activate adhesion, which can be impractical and lead to premature adhesion to undesired substrates due to isostatic compression and time-temperature superposition principles, especially when used with frangible or compressible substrates.

Innovation Solution

A substrate with microcapsules containing a plasticizer attached with a polymeric material, where the microcapsules are positioned above the polymeric layer, allowing for controlled adhesion by rupturing and releasing the plasticizer to soften the polymeric material, thus becoming tacky only when needed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If microcapsules are completely embedded within the pressure sensitive adhesive layer, then the adhesive structure is simple and complete, but very high pressures are required to cause capsule rupture and activate adhesion

Engineering Contradiction:
Improveadhesive structureVSAvoidactivation pressure
Core Design Contradiction:
Device complexityVSStress or pressure

Solution Approach 1:

The adhesive system is segmented into two functional layers: a non-tacky support layer containing embedded microcapsules and a separate tacky adhesive layer. This segmentation allows the microcapsules to be positioned in the support layer where they can rupture at lower pressures, eliminating the need for very high activation pressures while maintaining structural completeness.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The microcapsules are positioned at the interface between the support layer and adhesive layer, utilizing the vertical dimension to optimize their location. This dimensional arrangement allows the capsules to be accessible to lower pressures from the adhesive layer while remaining embedded in the overall structure, resolving the contradiction between structural completeness and activation pressure requirements.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Stability of the object's composition

If microcapsules are embedded within the adhesive layer, then adhesion is contained within the layer, but isostatic compression occurs requiring impractically high pressures

Engineering Contradiction:
Improveadhesive containmentVSAvoidisostatic compression pressure
Core Design Contradiction:
Stability of the object's compositionVSStress or pressure

Solution Approach 1:

By segmenting the adhesive system into a support layer and a separate adhesive layer, the microcapsules are contained within the support layer rather than the adhesive layer itself. This maintains compositional stability and containment while avoiding the isostatic compression problem that occurs when capsules are embedded within the fluid-like adhesive matrix.

Inventive Principle:
Principle #1Segmentation

3Duration of action of moving object

If the adhesive follows time-temperature superposition principle, then the material behaves as expected over time, but the surface builds adhesion over extended periods leading to premature adhesion

Engineering Contradiction:
Improveadhesive behavior time scaleVSAvoidpremature adhesion prevention
Core Design Contradiction:
Duration of action of moving objectVSReliability

Solution Approach 1:

The tacky adhesive properties are extracted from the microcapsule-containing support layer and placed in a separate adhesive layer. The support layer with embedded microcapsules remains non-tacky, preventing premature adhesion over extended periods. Adhesion is only activated when microcapsules rupture and release their contents into the separate adhesive layer, ensuring reliability by decoupling long-term stability from adhesion activation.

Inventive Principle:
Principle #2Taking out (Extraction)

4Reliability

If protective liners are used to prevent premature adhesion, then adhesion control is achieved, but significant costs are added and the liners are discarded before use

Engineering Contradiction:
Improvepremature adhesion preventionVSAvoiddiscarded liner cost
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The protective liner function is extracted and replaced by the non-tacky support layer containing embedded microcapsules. This support layer inherently prevents premature adhesion without requiring a separate discarded liner, eliminating the associated costs and waste while maintaining reliability in preventing unwanted adhesion.

Inventive Principle:
Principle #2Taking out (Extraction)

5Adaptability or versatility

If the adhesive is on a delicate backing such as nonwoven insulation material, then the adhesive can be applied to sensitive substrates, but the force required to remove the liner can damage the backing

Engineering Contradiction:
Improvesubstrate compatibilityVSAvoidbacking damage resistance
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The liner removal function is extracted and replaced by the microcapsule rupture mechanism. Since the support layer with embedded microcapsules is inherently non-tacky, no liner removal is needed. The adhesive activates when microcapsules rupture upon contact with the delicate substrate, eliminating the damaging removal force while maintaining versatility for sensitive substrates.

Inventive Principle:
Principle #2Taking out (Extraction)

6Reliability

If liners cover the entire surface of the substrate, then adhesion protection is comprehensive, but the cost increases and the adhesive location control is reduced

Engineering Contradiction:
Improveadhesion protection coverageVSAvoidliner material cost
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The adhesive functionality is applied locally through the separate adhesive layer rather than requiring comprehensive liner coverage. The microcapsule-containing support layer provides localized adhesion activation only where and when needed, reducing liner material costs while maintaining reliable adhesion protection through the non-tacky support layer structure.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables on-demand adhesion without the need for protective liners or high pressures, reducing costs and preventing premature adhesion to undesired substrates, while allowing for precise control over adhesion location and timing.

Implementation Method 1

a plasticizer encapsulated in the microcapsules... rupturing and releasing the plasticizer to soften the polymeric material

Methodology Applied
Scientific EffectPlasticizer softening:

Data Source

PatentUS11306431B2Articles including microcapsules for on-demand adhesion and methods of making same
Publication Date: 2022.04.19 3M INNOVATIVE PROPERTIES CO
  • US11306431B2 patent drawing

AI summary

Articles are provided, including a substrate having a first major surface, the substrate including a nonwoven material, a woven material, or a foam. The article further includes microcapsules having an outer surface and a plasticizer encapsulated in the microcapsules, where the plurality of microcapsules is attached to the first major surface of the substrate with a polymeric material. A method of making an article is also provided, including providing a substrate having a first major surface and providing microcapsules having an outer surface and a plasticizer encapsulated in the microcapsules. The method further includes attaching the microcapsules to the first major surface of the substrate with a polymeric material, thereby forming a polymeric matrix attached to the first major surface of the substrate.