Permeable Microcapsule Fabric for Low-Pressure CO2 Separation

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Solution Overview

Problem

Current microcapsule applications for gas treatment face challenges such as low capsule weight leading to inefficiencies in fluidized beds and high back pressure in fixed-bed systems due to limited gas passage, resulting in poor utilization of bed volume and short capsule lifetimes.

Innovation Solution

A permeable microcapsule embedded fabric with a three-dimensional solid media system that includes polymer surface layers and encapsulated stripping solvents, integrated into a fabric structure using additive manufacturing for efficient absorption and separation of carbon dioxide from flue gases, allowing for both static and dynamic use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If microcapsules are used in fluidized beds, then gas treatment is achieved, but capsule weight is too low leading to inefficiencies

Engineering Contradiction:
Improvecapsule weightVSAvoidfluidized bed efficiency
Core Design Contradiction:
Weight of moving objectVSProductivity

Solution Approach 1:

The patent combines multiple microcapsules into clusters or aggregates, merging them into larger functional units. This increases the effective weight and size of the treatment media while maintaining the high surface area-to-volume ratio of individual capsules, thereby improving fluidized bed efficiency and reducing entrainment losses.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses composite structures where microcapsules are embedded in a porous support matrix or combined with heavier particulate materials. This creates a composite media that maintains the absorption functionality of the microcapsules while achieving sufficient weight and density for efficient fluidized bed operation.

Inventive Principle:
Principle #40Composite materials

2Productivity

If microcapsules are packed in fixed beds, then gas contact is improved, but back pressure increases due to limited gas passage

Engineering Contradiction:
Improvegas contact efficiencyVSAvoidback pressure
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent employs porous support matrices or porous aggregate structures that provide extensive internal surface area for gas-liquid contact while maintaining open pore channels for gas flow. This allows high productivity through increased contact area without proportionally increasing back pressure, as the porous structure permits gas permeation.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent segments the fixed bed into multiple layers or zones with different capsule densities or sizes, creating channels and pathways for gas flow. This segmentation prevents complete blockage of gas passage while maintaining high contact efficiency in different regions of the bed.

Inventive Principle:
Principle #1Segmentation

3Productivity

If capsule density is increased to improve bed volume utilization, then absorption capacity increases, but capsule lifetime decreases

Engineering Contradiction:
Improvebed volume utilizationVSAvoidcapsule lifetime
Core Design Contradiction:
ProductivityVSDuration of action of moving object

Solution Approach 1:

By clustering microcapsules into groups, the patent achieves high effective density in the bed while individual capsules remain protected within the cluster structure. This reduces mechanical stress and abrasion on individual capsules, extending their lifetime while maintaining high bed volume utilization through the clustered configuration.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables effective absorption and separation of carbon dioxide with reduced back pressure and improved capsule longevity, enhancing the utilization of bed volume and maintaining efficient gas contact, thus addressing the limitations of existing microcapsule applications.

Implementation Method 1

an permeable microcapsule embedded fabric that acts as a sorbent that creates mold-able, variable geometry fabrics for static or dynamic use. The fabric is composed of micro encapsulated solvent spheres held together by structural members. The inventor's apparatus, systems, and methods provide an excellent means to absorb and separate gases and/or liquids

Methodology Applied
Scientific EffectGas absorption: Absorption (physical)

Implementation Method 2

Each of the capsules is permeable to a first gas of a mixture of gasses comprising the first gas and a second gas. Each of the capsules is substantially impermeable to the second gas. A liquid is disposed in each of the capsules that is permeable to the first gas and substantially impermeable to the second gas.

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS10183251B2Microcapsule fabric for absorption and release
Publication Date: 2019.01.22 LAWRENCE LIVERMORE NAT SECURITY LLC
  • US10183251B2 patent drawing
  • US10183251B2 patent drawing
  • US10183251B2 patent drawing

AI summary

A permeable microcapsule embedded fabric acts as a sorbent that creates mold-able, variable geometry fabrics for static or dynamic use. The fabric is composed of micro encapsulated solvent spheres held together by structural members. The fabric provides an excellent means to absorb and separate gases and/or liquids, particularly to separate carbon dioxide from flue gases.