Microcapsule Permeability Control via Amine-Modified Vinyl Monomers

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Solution Overview

Problem

Existing microencapsulation methods are limited by high permeability in products with surfactants or water, restricted formulation capabilities, limited breadth of encapsulable agents, stability issues, and inadequate deposition on treated surfaces, leading to premature release or mechanical instability of encapsulated agents.

Innovation Solution

The development of microcapsules formed through oil-in-water or water-in-oil emulsifications using amine modified polyvinyl monomers and bi- or polyfunctional vinyl monomers with free radical initiators, which control permeability by adjusting cross-linking time and temperature, allowing for low leakage or controlled release profiles and adherence to surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional microencapsulation methods are used, then capsule formation is achieved, but high permeability occurs in products with surfactants or water leading to premature release

Engineering Contradiction:
Improvecapsule stabilityVSAvoidpremature release
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the capsule wall by using amine-modified polyvinyl monomers with bi- or polyfunctional vinyl monomers, and controls physical parameters such as cross-linking time and temperature to achieve low permeability and controlled release

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite capsule walls by combining amine-modified polyvinyl monomers with bi- or polyfunctional vinyl monomers through cross-linking reactions, forming a composite material structure that provides both stability and controlled permeability

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional microencapsulation methods are used, then capsule formation is achieved, but mechanical instability occurs leading to inadequate deposition on surfaces

Engineering Contradiction:
Improvemechanical stabilityVSAvoidadherence to surfaces
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent adjusts cross-linking parameters (time and temperature) to optimize the balance between mechanical strength and surface adherence, achieving both stability and proper deposition

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If conventional microencapsulation methods are used, then capsule formation is achieved, but restricted formulation capabilities and limited breadth of encapsulable agents occur

Engineering Contradiction:
Improveformulation capabilitiesVSAvoidprocess complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The amine-modified polyvinyl monomer system provides universal encapsulation capability for various agents (surfactants, oils, fragrances, functional materials) through a single cross-linking mechanism, enhancing formulation versatility without requiring different processes for different materials

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting microcapsules exhibit improved permeability control, stability, and adherence, enabling the encapsulation of a wide range of agents with targeted release profiles and enhanced performance in consumer products.

Implementation Method 1

heating for a time and temperature sufficient to decompose the free radical initiators in the oil and water phases

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 2

decompose the free radical initiators in the oil and water phases; thereby forming microcapsule wall material at the interface of the water and oil phases

Methodology Applied
Scientific EffectFree radical polymerization: Photopolymerisation

Implementation Method 3

control permeability by adjusting cross-linking time and temperature

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Data Source

PatentUS9993793B2Delivery particles
Publication Date: 2018.06.12 PROCTER & GAMBLE CO

AI summary

The present application relates to encapsulated benefit agents, compositions comprising such encapsulated benefit agents and processes for making and using compositions comprising such encapsulated benefit agents. Such encapsulated benefit agents eliminate or minimize one or more of the drawbacks of current encapsulated benefit agents and thus provide formulators with additional perfume delivery opportunities.