Microcapsule Shell Strength via Composite Wax and Saccharide Layers

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Solution Overview

Problem

Existing microcapsules face challenges with susceptibility to rupture and reduced loading capacity due to increased wall thickness, and they lack effective impermeability and oxidative barriers, especially when encapsulating substances that are sensitive to oxygen.

Innovation Solution

The development of multicore microcapsules with enhanced shell structures using waxes, saccharides, proteins, and small molecules to block pores and increase crosslinks, resulting in improved structural strength, impermeability, and high payload capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the thickness of the microcapsule wall is increased to improve strength and impermeability, then the structural strength and impermeability are improved, but the loading capacity of the microcapsule is reduced

Engineering Contradiction:
Improvemicrocapsule wall strengthVSAvoidloading capacity
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent applies composite materials by combining gelatin with waxes (beeswax, paraffin wax, carnauba wax) and saccharides to create a multi-component shell structure. This composite approach enhances the mechanical strength and impermeability of the shell without requiring excessive wall thickness, thereby maintaining higher loading capacity. The synergistic interaction between these materials provides both structural integrity and barrier properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements local quality by creating a multi-layered shell structure where different materials are positioned at different layers. The gelatin provides the base structure, while wax and saccharide layers are applied specifically to enhance impermeability and oxidative barrier properties at critical interfaces. This localized enhancement allows for optimized protection without uniformly increasing wall thickness throughout the entire shell.

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If conventional microcapsule shells are used, then the microcapsules can be easily manufactured, but they exhibit poor oxidative barrier properties and reduced stability against oxygen

Engineering Contradiction:
ImprovemanufacturabilityVSAvoidoxidative damage from oxygen
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent combines gelatin with waxes and saccharides to create a composite shell that maintains ease of manufacture through established coacervation techniques while adding superior oxidative barrier properties. The wax and saccharide components are integrated into the shell formation process, allowing for straightforward manufacturing without complex additional steps.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the shell by incorporating materials with different oxygen permeability characteristics. The waxes and saccharides have lower oxygen permeability compared to gelatin alone, and their inclusion at specific concentrations (e.g., 0.1-10% wax, 1-20% saccharide) transforms the shell's oxidative barrier properties while maintaining manufacturability.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If single-core microcapsules are used, then the structure is simple, but they are highly susceptible to rupture

Engineering Contradiction:
Improvestructural simplicityVSAvoidresistance to rupture
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent uses composite materials to strengthen the single-core microcapsule shell, combining gelatin with wax and saccharide components that provide enhanced mechanical strength and flexibility. This composite structure increases rupture resistance while maintaining the simplicity of the single-core configuration and avoiding the complexity of multi-core designs.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by concentrating the reinforcing materials (wax and saccharides) at specific locations within the shell structure, particularly at the interface between the core and shell and at potential stress concentration points. This localized reinforcement enhances rupture resistance without requiring a complete redesign of the overall simple single-core structure.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The enhanced microcapsules exhibit extended induction periods, improved oxidative stability, and increased payload capacity, effectively protecting encapsulated substances from oxygen and maintaining stability and sensory properties.

Implementation Method 1

The enhanced microcapsules exhibit extended induction periods, improved oxidative stability, and increased payload capacity, effectively protecting encapsulated substances from oxygen

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP2040682B1Microcapsules with improved shells
Publication Date: 2017.07.26 DSM NUTRITIONAL PRODUCTS AG
  • EP2040682B1 patent drawingFigure 1a~1d
  • EP2040682B1 patent drawingFigure 2
  • EP2040682B1 patent drawingFigure 3

AI summary

Disclosed are microcapsules and methods for preparing and using them, as well as methods for improving various properties of microcapsules like impermeability.