Biodegradable Microcapsules via Polyelectrolyte Coacervation

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Solution Overview

Problem

Current methods for producing microcapsules, particularly those using synthetic resins, contribute to environmental microplastic pollution and fail to meet industrial needs for high stability and controlled release, while existing polyelectrolyte-based methods are not suitable for industrial production or result in unsatisfactory microcapsules.

Innovation Solution

A method involving the coacervation of solubilized polyelectrolytes, such as chitosan and gum arabic, where the core material is emulsified and pH is adjusted to induce coacervation, producing biodegradable microcapsules with high encapsulation efficiency and stability, avoiding the use of synthetic resins and reducing microplastic contamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If synthetic resins are used to produce microcapsules, then stability and impermeability are improved, but environmental pollution increases

Engineering Contradiction:
ImprovestabilityVSAvoidenvironmental pollution
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the material parameter from synthetic resin to natural polyelectrolytes (chitosan and gum arabic), transforming the chemical composition while maintaining the functional properties of stability and impermeability through coacervation-based encapsulation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite shell structure formed by coacervation of two natural polyelectrolytes (chitosan and gum arabic), creating a biodegradable composite material that provides both environmental friendliness and structural stability

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If coacervation of polyelectrolytes is used to produce microcapsules, then environmental friendliness is improved, but manufacturing suitability and quality are worsened

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidmanufacturing suitability
Core Design Contradiction:
Object-generated harmful factorsVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-solubilizing both polyelectrolytes in the same composition before emulsification, ensuring they are ready for immediate coacervation upon pH adjustment, which streamlines the manufacturing process

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses pH value adjustment as a critical parameter change to trigger coacervation, transforming the solubilized polyelectrolyte mixture into an encapsulating shell structure, providing a simple and controllable manufacturing step

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If coacervation of polyelectrolytes is used to produce microcapsules, then environmental friendliness is improved, but encapsulation quality is worsened

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidencapsulation quality
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The patent optimizes encapsulation quality by precisely controlling the pH value parameter during coacervation, ensuring the formation of a stable and impermeable shell structure that provides high encapsulation efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite shell made of chitosan and gum arabic polyelectrolytes that work synergistically to provide both environmental biodegradability and high encapsulation quality with controlled release properties

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the production of environmentally friendly, stable, and impermeable microcapsules with controlled release profiles, suitable for industrial applications, achieving high yield and resistance to evaporation and destabilization, even in harsh environments.

Implementation Method 1

initiating the coacervation by changing the pH value into the pH range wherein coacervation of the polyelectrolytes occurs

Methodology Applied
Scientific EffectCoacervation: Coacervate

Implementation Method 2

emulsifying/suspending a core material in this solution in a further step

Methodology Applied
Scientific EffectEmulsion: Emulsion

Data Source

PatentUS20240017234A1Improved microcapsules and method for the production and use thereof
Publication Date: 2024.01.18 FOLLMANN GMBH & CO KG
  • US20240017234A1 patent drawing
  • US20240017234A1 patent drawing
  • US20240017234A1 patent drawing

AI summary

The present invention is directed to a method for producing environmentally friendly microcapsules. Moreover, the present invention provides microcapsules obtained/obtainable by the method according to the invention, in particular multilayer microcapsules which are suitable for all kinds of industrial application, in particular in personal care and home care products. The microcapsules preferably comprise at least one oil as core material.