3D Microelectrode Self-Organized Folding via Strain Gradient

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Solution Overview

Problem

Existing techniques for creating three-dimensional graphene microelectrodes face issues with adhesion and stress concentration, leading to peeling, slippage, and breakage, while two-dimensional structures limit design flexibility.

Innovation Solution

A microelectrode with a layered structure comprising a polymer compound layer and a conductive layer, where the polymer compound layer contains aromatic rings and the conductive layer is made of carbon materials, allowing for self-organized three-dimensional folding using a strain gradient.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If graphene is transferred to a thin film element for self-organized folding, then three-dimensional shape capability is improved, but adhesion is insufficient causing peeling and slippage

Engineering Contradiction:
Improvethree-dimensional shape capabilityVSAvoidadhesion strength
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent uses a composite structure consisting of a polymer compound layer containing aromatic rings and a conductive layer containing graphene. The aromatic rings in the polymer layer provide strong interaction sites for graphene, enhancing adhesion while allowing the composite structure to achieve self-organized three-dimensional folding through strain gradients.

Inventive Principle:
Principle #40Composite materials

2Reliability

If parylene is used as the polymer substrate, then adhesion to graphene is improved, but design flexibility is reduced due to two-dimensional plane structure

Engineering Contradiction:
Improveadhesion strengthVSAvoiddesign flexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent transitions from a two-dimensional plane structure to a three-dimensional curved shape by utilizing strain gradients within the layered composite structure. This dimensional change enables design flexibility while maintaining the strong adhesion properties provided by the aromatic ring-containing polymer compound layer.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Shape

If artificial buckling is used to create three-dimensional shape, then shape capability is improved, but manufacturing precision is reduced and local stress concentration occurs

Engineering Contradiction:
Improvethree-dimensional shape capabilityVSAvoidshape control precision
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The patent employs self-organized folding where the layered composite structure automatically forms three-dimensional curved shapes through internal strain gradients without requiring external artificial buckling. This self-service mechanism eliminates local stress concentration and improves manufacturing precision by avoiding forced deformation.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables the creation of microelectrodes with stable three-dimensional curved shapes, preventing peeling, slippage, and breakage, while maintaining electrical conductivity and flexibility for various applications.

Implementation Method 1

graphene itself applies a strain gradient to the thickness direction of the thin film, so that graphene itself functions as a power source for self-organized three-dimensional folding

Methodology Applied
Scientific EffectSelf-organized folding: Self-Assembly

Implementation Method 2

a strained state in which a strain gradient is applied in a thickness direction of the thin film

Methodology Applied
Scientific EffectStrain gradient: Deformation

Data Source

PatentUS11927558B2Microelectrode, method of manufacturing same, and integrated device
Publication Date: 2024.03.12 NIPPON TELEGRAPH & TELEPHONE CORP
  • US11927558B2 patent drawing
  • US11927558B2 patent drawing
  • US11927558B2 patent drawing

AI summary

Provided is a microelectrode having a layered structure, including a layer containing a polymer compound having an aromatic ring (polymer compound layer) and a layer containing a conductive material (conductive layer), wherein a thickness of the polymer compound layer is 10 to 900 nm, a thickness of the conductive layer is 0.3 to 10 nm, and the microelectrode has a three-dimensional curved shape.