Oil-in-Water Microemulsion for High Transparency and Cleansing

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Solution Overview

Problem

Existing cosmetic compositions, particularly oil-in-water type microemulsions, face challenges in achieving high transparency, stability, and cleansing power while maintaining a good feel on the skin, especially when used with cotton or as a pump foamer, and struggle with affinity to both water-based and oil-based makeup stains.

Innovation Solution

A cosmetic composition comprising at least one type of oil, a polyglycerol fatty acid monoester with an HLB value of 11 to 18, a polyglycerol fatty acid diester or triester with an HLB value of 10 to 13, an anionic surfactant, and water, with specific mass ratios and viscosity ranges to form a stable oil-in-water microemulsion that enhances cleansing power and feel.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polyglycerol fatty acid esters are used as non-ionic surfactant to form microemulsion, then the microemulsion can be formed with high safety, but the emulsifying capacity is low and a large amount must be added, and stability is insufficient with possibility of creaming

Engineering Contradiction:
ImprovesafetyVSAvoidemulsifying capacity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent combines polyglycerol fatty acid esters with specific auxiliary emulsifying agents (2-hydroxy fatty acids with 10-22 carbon atoms or betaine acids) to create a composite surfactant system. This composite approach enhances the emulsifying capacity and stability while maintaining the safety benefits of polyglycerol fatty acid esters, resolving the contradiction between safety and emulsifying performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent specifies precise parameter ranges for the auxiliary emulsifying agents (2-hydroxy fatty acids with 10-22 carbon atoms or betaine acids) to optimize the microemulsion formulation. By controlling the type and amount of auxiliary agents, the system achieves high emulsifying capacity and stability while maintaining safety, addressing the limitations of using polyglycerol fatty acid esters alone.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If water-in-oil type microemulsion is used as cleansing cosmetic, then a larger amount of water can be added and cleansing power is maintained on wet skin, but the affinity to water-based makeup stains is lower and cleansing power against such stains is reduced

Engineering Contradiction:
Improveamount of waterVSAvoidaffinity to water-based makeup stains
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent inverts the conventional water-in-oil microemulsion structure to create an oil-in-water type microemulsion. This inversion allows the system to maintain high water content while improving affinity to water-based makeup stains through the synergistic effect of low interfacial tension and added oil, resolving the contradiction between water content and stain affinity.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The patent optimizes the oil-to-water ratio and surfactant composition in the oil-in-water microemulsion to achieve both high water content and effective cleansing of water-based makeup stains. By carefully controlling the parameters of oil phase, water phase, and surfactant system, the formulation maintains versatility against different types of makeup stains while incorporating significant amounts of water.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If water-in-oil type microemulsion is used, then the structure provides high cleansing effects, but the viscosity is higher than water-based form and the ability to use with cotton is lost

Engineering Contradiction:
Improvecleansing effectsVSAvoidviscosity and usability with cotton
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent inverts the microemulsion structure from water-in-oil to oil-in-water type, which fundamentally changes the viscosity characteristics. The oil-in-water structure with specific surfactant combinations achieves low viscosity that enables use with cotton and pump foamers while maintaining high cleansing effects through the synergistic action of surfactants and oil phase.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The patent controls the viscosity parameter by optimizing the surfactant concentration, oil phase composition, and water-to-oil ratio in the oil-in-water microemulsion. This parameter optimization ensures the product has sufficiently low viscosity for cotton application and pump foamer compatibility while preserving effective cleansing performance.

Inventive Principle:
Principle #35Parameter changes

4Illumination intensity

If oil-in-water type microemulsion is used, then the transparency can be maintained by minimizing interfacial tension, but the cleansing power needs improvement through synergistic effect of low interfacial tension and added oil

Engineering Contradiction:
ImprovetransparencyVSAvoidcleansing power
Core Design Contradiction:
Illumination intensityVSProductivity

Solution Approach 1:

The patent creates a composite system combining oil phase, water phase, and specifically selected surfactants (polyglycerol fatty acid esters with auxiliary emulsifying agents) to achieve synergistic effects. This composite formulation maintains transparency through low interfacial tension while simultaneously enhancing cleansing power against both water-based and oil-based makeup stains.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the interfacial tension parameter by selecting and combining specific surfactants with appropriate HLB values. This parameter control ensures transparency is maintained while the optimized surfactant system, working synergistically with the oil phase, delivers enhanced cleansing power against various types of makeup stains.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves high transparency, stability, and effective cleansing of both water-based and oil-based makeup stains with low stickiness and a refreshing feel, suitable for use with cotton or as a pump foamer, and is suitable for both cleansing and leave-on cosmetic applications.

Implementation Method 1

The oil-in-water type microemulsion needs to minimize the interfacial tension to maintain the transparency and improves the cleansing power by the synergistic effect of the low interfacial tension and the oil to be added

Methodology Applied
Scientific EffectInterfacial tension reduction: Surfactant

Implementation Method 2

A cosmetic composition in a form of an oil-in-water type microemulsion, comprising: (a) at least one type of an oil; (b) at least one type of a polyglycerol fatty acid monoester; (c) at least one type of a polyglycerol fatty acid diester or a polyglycerol fatty acid triester; (d) at least one type of an anionic surfactant; and (e) water

Methodology Applied
Scientific EffectMicroemulsion formation: Microemulsion

Implementation Method 3

The microemulsion is a system that makes a larger amount of an oil (or water) soluble than a general micelle solution (or a reverse micelle oil solution) and is an isotropic solution having the transparent to blue appearance

Methodology Applied
Scientific EffectIsotropic solution formation: Microemulsion

Data Source

PatentUS12083203B2Cosmetic composition
Publication Date: 2024.09.10 MERRY PLUS CORP

AI summary

One object is to provide a cosmetic composition having high transparency, high stability, good feeling of use and high cleansing power. There is provided a cosmetic composition in a form of an oil-in-water type microemulsion, comprising: (a) at least one type of an oil; (b) a polyglycerol fatty acid monoester having an HLB value of 11 to 18; (c) a polyglycerol fatty acid diester or a polyglycerol fatty acid triester having an HLB value of 10 to 13 and having an alkyl chain or an alkenyl chain of ten to fourteen carbon atoms; (d) an anionic surfactant; and (e) water, wherein a mass ratio of the (c) polyglycerol fatty acid diester or polyglycerol fatty acid triester to the (b) polyglycerol fatty acid monoester is 0.01 to 1.65, and a ratio of a total mass of the (b) the polyglycerol fatty acid monoester and the (c) polyglycerol fatty acid diester or polyglycerol fatty acid triester to a mass of the (a) oil is 1 to 550.