Microencapsulated Essential Oil Stability via Segmentation

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Solution Overview

Problem

Essential oils face challenges due to volatility, poor water solubility, and susceptibility to oxidation, making them difficult to use effectively as control systems for agricultural and food storage applications.

Innovation Solution

Microencapsulation of essential oils using a method involving alkanoic acids, aqueous basic solutions, and multivalent cations to form stable microcapsules that can be used as preservatives, disinfectants, and insect repellents, with controlled release and distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If essential oils are used directly, then they have antimicrobial and insecticidal activity, but they suffer from volatility, poor water solubility, and oxidation susceptibility

Engineering Contradiction:
Improvestability of essential oilVSAvoidvolatility and oxidation of essential oil
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The essential oil is segmented into microcapsules, dividing the bulk liquid into numerous small discrete units. Each microcapsule contains a tiny amount of essential oil protected by a shell, preventing bulk oxidation and reducing volatility while maintaining the total antimicrobial and insecticidal activity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A flexible shell material is formed around the essential oil to create microcapsules. This shell protects the essential oil from oxidation and prevents volatility, while still allowing controlled release of the active ingredients when needed for antimicrobial and insecticidal action.

Inventive Principle:
Principle #30Flexible shells and thin films

2Reliability

If essential oils are encapsulated to improve stability, then volatility and oxidation are reduced, but water solubility remains poor

Engineering Contradiction:
Improvestability of essential oilVSAvoidwater solubility of essential oil
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The microcapsule shell is designed with amphiphilic properties, having both hydrophobic regions that interact with the essential oil and hydrophilic regions that interact with water. This allows the microcapsules to disperse uniformly in aqueous environments, effectively solving the water solubility problem while maintaining the protective enclosure.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The microcapsule structure combines hydrophobic materials (for essential oil compatibility) with hydrophilic materials (for water dispersibility). This composite approach creates a material that bridges the incompatibility between oil and water, enabling stable aqueous formulations.

Inventive Principle:
Principle #40Composite materials

3Ease of operation

If microencapsulation is applied to improve delivery, then controlled release is achieved, but the formulation complexity increases

Engineering Contradiction:
Improvedelivery efficiency of essential oilVSAvoidcomplexity of microencapsulation formulation
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The shell material composition and thickness are optimized to achieve the desired controlled release profile. By adjusting parameters such as crosslinking density, shell thickness, and material hydrophobicity, the release rate can be tuned without fundamentally changing the microencapsulation approach, simplifying formulation development.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The microencapsulated essential oils provide effective antimicrobial and insecticidal properties, improving their stability and application efficacy in various non-agricultural uses, including mastitis prevention and insect repellency.

Implementation Method 1

admixing into the suspension of step (b) an aqueous salt solution comprising at least one multivalent cation, thereby obtaining a suspension of microcapsules comprising said at least one essential oil

Methodology Applied
Scientific EffectComplexation:

Implementation Method 2

release rates from the microcapsules, degrees of permeability

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS9717240B2Applications of microencapsulated essential oils
Publication Date: 2017.08.01 BIO LEAF LTD

AI summary

Method for the preparation of microencapsulated essential oils or a formulation thereof for various non-agricultural applications.