Two-Component Microencapsulation for Hydrocarbon Detoxification

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Solution Overview

Problem

Current remediation technologies for hydrocarbon spills and chemical biological agents are limited in effectiveness, with existing methods struggling to efficiently remove hydrocarbons from soil and surfaces, and existing decontamination solutions for chemical biological agents being slow, corrosive, or leaving residues.

Innovation Solution

A two-component water-based micro encapsulation system that uses an alkaline silicate formulation followed by an acidic polymer formulation to convert liquid organic wastes into solid materials, significantly reducing aqueous leachability and incorporating a detoxifying agent for rapid detoxification and micro encapsulation of hazardous substances.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If macro encapsulation technologies are used to bind contaminants into a solid matrix, then contaminant leaching is reduced, but the technology is limited primarily to inorganic contaminants and works poorly with organic contaminants

Engineering Contradiction:
Improvecontaminant binding effectivenessVSAvoidapplicability to organic contaminants
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The invention changes the fundamental parameters of encapsulation technology by transitioning from macro-scale cementitious binding to micro-scale emulsion-based encapsulation. The use of microemulsion droplets (1-100 micrometers) with surfactant-stabilized interfaces creates a completely different physical-chemical regime that is highly effective for organic contaminants while maintaining contaminant immobilization.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite microencapsulation system combining surfactants, polymers, and inorganic particles within emulsion droplets. This multi-component composite structure provides both the binding capability for organic contaminants and the solid matrix stability needed for long-term immobilization, overcoming the limitations of single-material approaches.

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing decontamination solutions are used for chemical biological agents, then detoxification occurs, but the process is slow, corrosive, or leaves residues

Engineering Contradiction:
Improvedetoxification effectivenessVSAvoidcorrosiveness and residues
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and isolates hazardous contaminants within microemulsion droplets, separating them from the surrounding environment. The surfactant barrier prevents harmful interactions with surfaces and materials, eliminating corrosiveness while maintaining detoxification effectiveness through contained treatment.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system transforms hazardous contaminants into less harmful forms through detoxification processes occurring within the microemulsion, then immobilizes the treatment products and any remaining contaminants in a stable solid matrix that can be safely disposed of or recovered, eliminating persistent residues.

Inventive Principle:
Principle #34Discarding and recovering

3Reliability

If soil remediation technologies are used to remove hydrocarbons, then contaminant removal is achieved, but the ease of removal varies significantly and many contaminants are resistant to degradation

Engineering Contradiction:
Improvecontaminant removal effectivenessVSAvoidease of contaminant removal
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The invention introduces surfactants as intermediary substances that mediate between the hydrophobic hydrocarbon contaminants and the aqueous treatment environment. These surfactants reduce interfacial tension, emulsify contaminants, and enhance their accessibility to degradation processes, dramatically improving ease of removal for resistant contaminants.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The system performs preliminary emulsification and stabilization of contaminants within microemulsion droplets before final immobilization or degradation. This preliminary action transforms difficult-to-remove contaminants into a form that is much easier to handle, treat, and remove, simplifying subsequent remediation steps.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively micro encapsulates hydrocarbons and chemicals into a non-leachable form, rapidly detoxifies highly hazardous materials, and achieves complete loss of spore viability within minutes, providing a stable and environmentally friendly solution for cleanup and decontamination.

Implementation Method 1

a two-component water based micro encapsulation composition and method for the cleanup of hydrocarbon spills or contaminates

Methodology Applied
Scientific EffectMicro encapsulation:

Implementation Method 2

incorporating a detoxifying agent for rapid detoxification and micro encapsulation of hazardous substances

Methodology Applied
Scientific EffectDetoxification:

Implementation Method 3

achieves complete loss of spore viability within minutes

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS8115046B2Micro encapsulation composition for hydrocarbons and detoxification of highly hazardous chemicals and substances
Publication Date: 2012.02.14 OIL SOLUTIONS INT
  • US8115046B2 patent drawing
  • US8115046B2 patent drawing
  • US8115046B2 patent drawing

AI summary

A two-component, water based micro encapsulation composition and method for the cleanup of hydrocarbon spills or contaminates on various surfaces and media. The two-part formulation includes a first solution including water in a predetermined ratio of a water soluble alkaline silicate solution having at least one alkali metal and a predetermined ratio of at least one water soluble surfactant; and a second solution including water, a predetermined ratio of water soluble acid, a predetermined ratio of water dispersible polymer, a predetermined ratio of water soluble hydrotrope, and a predetermined ratio of at least one water soluble flocculating agent. A method of using the two-part formulation includes preparing the two-part formulation, allowing the first solution to contact the hydrocarbon or chemical contaminate; allowing the second solution to contact the first solution and contaminate to form a homogeneous mixture; and removing the homogeneous mixture.