Microfibrillar Cellulose Admixture for Concrete Segregation Control

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Solution Overview

Problem

Self-compacting concrete (SCC) faces issues with segregation and sensitivity to variations in raw materials, leading to unacceptable properties and reduced robustness, while injection grouts experience high fluidity and segregation problems due to high water-cement ratios, limiting their application.

Innovation Solution

The use of microfibrillar cellulose and/or its derivatives as a stabilizing admixture in concrete formulations, which form a continuous hydrogel network, reducing water bleeding and aggregate settlement, and enhancing thixotropy, thereby improving the robustness and durability of SCC and reducing segregation in injection grouts.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If high water-cement ratio is used in injection grouts to achieve high fluidity, then fluidity is improved, but segregation increases

Engineering Contradiction:
ImprovefluidityVSAvoidsegregation
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent introduces a stabilizing admixture comprising microfibrillar cellulose and/or its derivatives as an intermediary substance. This admixture forms a hydrogel network that acts as a mediator between water and cement particles, providing structural support to the grout mixture. The hydrogel network prevents water segregation and aggregate settlement while maintaining high fluidity, thus resolving the contradiction between ease of operation and compositional stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite system by combining microfibrillar cellulose, its derivatives, or labile chemically modified cellulose pulp with cement and water. This composite admixture forms a unique hydrogel network structure that integrates the properties of cellulose fibers and water, providing both fluidity and stability simultaneously. The composite nature of the admixture allows it to function as both a fluidity enhancer and a segregation inhibitor.

Inventive Principle:
Principle #40Composite materials

2Productivity

If self compacting concrete is used to eliminate compaction work, then productivity is improved, but segregation and sensitivity to raw material variations increase

Engineering Contradiction:
Improvecompaction work eliminationVSAvoidsegregation
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The stabilizing admixture acts as an intermediary hydrogel network that provides internal structural support to the self-compacting concrete mixture. This network mediates between the competing requirements of high flowability (for productivity) and compositional stability (to prevent segregation). The hydrogel structure allows the concrete to flow and compact itself while maintaining uniform distribution of components throughout the mixture.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the rheological parameters of the concrete mixture by introducing the microfibrillar cellulose-based admixture. This changes the flow behavior and thixotropy of the mixture, allowing it to maintain stability during the self-compaction process. The admixture adjusts the physical parameters of the fresh concrete to achieve both high productivity and reduced segregation sensitivity.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If viscosity enhancing agents like welan gum or cellulose derivatives are used to reduce segregation, then stability is improved, but the dosages required are high

Engineering Contradiction:
Improvesegregation controlVSAvoidadditive dosage
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent changes the physical state and structural parameters of the cellulose-based additive by using microfibrillar forms with diameters less than 1 μm (preferably less than 200 nm, more preferably less than 100 nm). This parameter change in fiber dimensions dramatically increases the surface area and networking capability per unit mass, allowing much lower dosages (0.002-0.2% by weight of cementitious binder) to achieve the same or better segregation control compared to conventional cellulose derivatives that require higher dosages.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a highly efficient composite structure using microfibrillar cellulose that forms a three-dimensional hydrogel network. This composite network structure provides exceptional segregation control at very low concentrations because the microfibrils create a more extensive and effective spatial framework compared to larger cellulose fibers or conventional viscosity modifiers. The composite nature of the hydrogel network maximizes the stabilizing effect per unit of additive.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The microfibrillar cellulose admixture effectively decreases water bleeding and aggregate settlement, increases thixotropy, and enhances the durability of SCC, allowing for higher water-cement ratios with improved stability and reduced segregation, thus making SCC more robust and suitable for wider applications.

Implementation Method 1

In aqueous environment microfibrillar cellulose forms a continuous hydrogel network of dispersed microfibrils or microfibril bundles

Methodology Applied
Scientific EffectHydrogel formation: Hydrogel

Implementation Method 2

The gel is formed by highly hydrated fibrils that are entangled between each other... The gel starts to flow at elevated shear stress... increases paste thixotrophy

Methodology Applied
Scientific EffectThixotropy: Thixotropy

Implementation Method 3

Due to the intrinsic properties of the microfibrillar cellulose gels, the materials also show strong aggregate suspending power... Aggregate settlement is also drastically decreased with microfibrillar cellulose

Methodology Applied
Scientific EffectSuspension: Suspension

Implementation Method 4

The use of microfibrillar cellulose and/or derivatives thereof increases paste thixotrophy both with and without plasticizer... water bleeding and aggregate settlement are diminished

Methodology Applied
Scientific EffectViscosity enhancement:

Data Source

PatentEP2493829B8Material to be used as a concrete additive
Publication Date: 2019.06.19 UPM KYMMENE OYJ

AI summary

The invention relates to an admixture for a cementitious composition comprising microfibrillar cellulose and/or a derivative thereof. The invention also relates to a method of manufacturing said admixture and to the use of the microfibrillar cellulose and/or a derivative thereof in the concrete admixture. The invention further relates to a cementitious composition comprising said admixture and methods of manufacture and use thereof.