Microfibrous Cellulose Composite Sheet Manufacturing

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Solution Overview

Problem

Current methods for manufacturing microfibrous cellulose composite sheets and laminates face challenges in achieving industrial productivity and efficiency, with existing techniques failing to effectively combine microfibrous cellulose with polymers while maintaining transparency and dimensional stability.

Innovation Solution

A method involving the mixing of a polymer emulsion with an aqueous suspension of microfibrous cellulose, followed by dehydration on a porous base material and drying, with the option to laminate sheets by thermal compression or applying a polymer layer, using cellulose coagulants like sodium chloride or cationic polymers to enhance properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If microfibrous cellulose is made into a composite with polymer, then thermal-resistant dimensional stability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvethermal-resistant dimensional stabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent combines microfibrous cellulose with polymer resin in a composite sheet structure, where the polymer matrix binds the cellulose microfibers together. This merging of materials achieves thermal-resistant dimensional stability while using standard composite manufacturing processes to control complexity

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a composite material system consisting of microfibrous cellulose dispersed in a polymer matrix. The composite structure leverages the dimensional stability of cellulose and the thermal resistance of polymer, achieving both properties simultaneously through material composition rather than complex processing

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If microfibrous cellulose sheet is made transparent by impregnating resin, then transparency is improved, but manufacturing complexity increases

Engineering Contradiction:
ImprovetransparencyVSAvoidmanufacturing complexity
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent applies resin impregnation specifically to fill the spaces between microfibrous cellulose sheets, targeting the regions that cause light scattering. This localized treatment improves transparency without requiring complete restructuring of the manufacturing process

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The polymer resin acts as an intermediary material that fills voids and spaces between cellulose microfibers. This intermediary substance eliminates air pockets that cause opacity, enabling transparency while using conventional impregnation techniques

Inventive Principle:
Principle #24Intermediary (Mediator)

3Illumination intensity

If microfibrous cellulose is produced by mechanical crushing to 50 nm or less, then transparency is improved, but productivity decreases

Engineering Contradiction:
ImprovetransparencyVSAvoidindustrial productivity
Core Design Contradiction:
Illumination intensityVSProductivity

Solution Approach 1:

The patent uses mechanical crushing to reduce cellulose fiber dimensions to microfibrous levels, applying sufficient force to achieve the necessary size reduction for transparency. The process uses standard industrial crushing equipment operating at optimized parameters to balance transparency achievement with manufacturing efficiency

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The invention changes the physical parameters of cellulose fibers through mechanical crushing, reducing fiber width to 50 nm or less. This parameter change enables transparency while using conventional mechanical processing methods to maintain industrial productivity

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If microfibrous cellulose is made into composite sheet with polymer emulsion, then ease of manufacture is improved, but manufacturing precision may be compromised

Engineering Contradiction:
Improveease of manufactureVSAvoidsheet formation precision
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent uses a papermaking machine that employs hydraulic and pneumatic principles in the filtration and drying sections. Water is removed through controlled filtration under pressure, and the sheet formation process uses fluid dynamics to achieve uniform distribution of microfibrous cellulose and polymer emulsion

Inventive Principle:
Principle #29Pneumatics and hydraulics

Solution Approach 2:

The invention controls the concentration and composition parameters of the polymer emulsion to optimize both ease of manufacture and sheet formation precision. By adjusting emulsion parameters such as polymer content, particle size, and pH, the process achieves good manufacturability while maintaining precise sheet properties

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the efficient production of microfibrous cellulose composite sheets and laminates with improved transparency, dimensional stability, and moisture resistance, suitable for applications in flexible substrates for organic ELs and liquid crystal displays.

Implementation Method 1

a polymer emulsion is mixed with an aqueous suspension including microfibrous cellulose

Methodology Applied
Scientific EffectMixing:

Implementation Method 2

the mixed fluid is dehydrated on a porous base material through filtration

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Implementation Method 3

a sheet including moisture is heated and dried

Methodology Applied
Scientific EffectDrying:

Implementation Method 4

a sheet including moisture is heated and dried

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 5

cellulose coagulants like sodium chloride or cationic polymers

Methodology Applied
Scientific EffectCoagulation: Coagulation

Implementation Method 6

the overlapped microfibrous cellulose composite sheets are thermally compressed

Methodology Applied
Scientific EffectThermal compression:

Data Source

PatentEP2460934B1Method for manufacturing microfibrous cellulose composite sheets and method for manufacturing microfibrous cellulose composite sheet laminate
Publication Date: 2017.03.08 OJI HLDG CORP
  • EP2460934B1 patent drawing
  • EP2460934B1 patent drawing
  • EP2460934B1 patent drawing

AI summary

The present invention provides a method for easily and efficiently manufacturing microfibrous cellulose composite sheets. The present invention is a method for manufacturing microfibrous cellulose composite sheets, including a preparation process in which a polymer emulsion is mixed with an aqueous suspension including microfibrous cellulose, thereby preparing a mixed fluid, a papermaking process in which the mixed fluid is dehydrated on a porous base material through filtration, and a sheet including moisture is formed, and a drying process in which the sheet including moisture is heated and dried. In addition, the present invention is a method for manufacturing a microfibrous cellulose composite sheet laminate, in which the microfibrous cellulose sheets are thermally compressed and thus laminated as they are or after being provided with a polymer layer on at least one surface thereof.