Microfine Ilmenite Weighting Agent Drilling Fluid Rheology

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Solution Overview

Problem

Existing drilling fluids and cement slurries face challenges with rheological properties and abrasiveness due to the use of coarser ilmenite and barite as weighting agents, which affect the stability and solubility of the mud filter cake, leading to issues with well completion and drilling fluid viscosity.

Innovation Solution

The use of microfine particulate ilmenite with a FeTiO3 content of at least 85% by weight, a specific surface area between 1 and 5 m^2/g, and particle sizes less than 12.5µm, along with high circularity, improves flow properties and solubility, reducing abrasiveness and viscosity changes during drilling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If coarser ilmenite and barite are used as weighting agents, then the density requirement is met, but the rheological properties deteriorate and abrasiveness increases

Engineering Contradiction:
ImprovedensityVSAvoidrheological properties
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies parameter changes by transitioning from coarser ilmenite particles to microfine ilmenite particles with significantly reduced particle size. This parameter change in particle dimensions transforms the rheological behavior of the drilling fluid, reducing viscosity and improving flow characteristics while maintaining the required density through high specific surface area of the microfine particles.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If coarser ilmenite and barite are used as weighting agents, then the density requirement is met, but abrasiveness increases affecting well completion

Engineering Contradiction:
ImprovedensityVSAvoidabrasiveness
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent utilizes parameter changes by reducing the particle size of ilmenite to microfine dimensions. This parameter modification significantly reduces the abrasiveness of the weighting agent while preserving its density contribution, thereby eliminating the harmful abrasive effects on drilling equipment and well completion operations.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If conventional weighting agents are used, then density is achieved, but mud filter cake stability deteriorates

Engineering Contradiction:
ImprovedensityVSAvoidmud filter cake stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by using microfine ilmenite particles with enhanced surface area characteristics. These parameter modifications improve the interaction between weighting agent particles and the mud filter cake structure, enhancing stability and preventing premature breakdown during drilling operations.

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If conventional weighting agents are used, then density is achieved, but plastic viscosity increases during drilling

Engineering Contradiction:
ImprovedensityVSAvoidplastic viscosity
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The patent employs parameter changes by transitioning to microfine ilmenite particles. This parameter modification in particle size and surface area reduces the plastic viscosity of the drilling fluid by improving particle distribution and reducing inter-particle friction, thereby reducing energy loss during circulation while maintaining density requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The microfine ilmenite enhances the stability and flow properties of drilling fluids and cement slurries, providing improved sag resistance, reduced plastic viscosity, and enhanced acid solubility, facilitating easier well completion and maintaining consistent rheological properties.

Implementation Method 1

drilling fluids and cement slurries must have the right density to counterbalance the downhole pressure in the formations

Methodology Applied
Scientific EffectGravitation: Gravitation

Implementation Method 2

The anionic cellulose is a water soluble polymer with a molecular weight of 200,000-400,000 and a degree of substitution of 0.7-1.3. The cellulose backbone is substituted with carboxylate groups which are ionized at the pH of the drilling fluid or cement slurry.

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 3

The carboxymethylated starch is a water soluble polymer with a molecular weight of 60,000-120,000 and a degree of substitution of 0.7-1.3

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2566931B1Oil well drilling fluids, oil well cement composition, and slurry of weighting material comprising ilmenite
Publication Date: 2017.09.27 ELKEM
  • EP2566931B1 patent drawingFigure 1
  • EP2566931B1 patent drawingFigure 2~3
  • EP2566931B1 patent drawingFigure 4~5

AI summary

The present invention relates to oil well drilling comprising a weighting agent consisting of microfine, particulate ilmenite having a FeTi03 content of at least 85% by weight, a specific surface area (BET) between 1 and 5 m2/g, where 90% by volume of the particles have a size of less than 12.5pm and a D50 between 3pm and 6pm by volume measured by laser diffraction using Malvern laser diffraction particle size analyzer, where the particles have an average circularity of at least 0.85 determined by image analysis. The invention further relates to high density oil well cement slurry comprising water, Portland cement, a weighting material and optionally silica flour, microsilica, fiber, rubbery particles a fluid loss addition and a retarder, where the weighting material is particulate microfine ilmenite having a FeTi03 content of at least 85% by weight, a specific surface area (BET) between 1 and 5 m2/g, and where 90% by volume of the particles have a size of less than 12.5pm and a D50 between 3 and 6pm measured by laser diffraction using Malvern laser diffraction particle size analyzer, and where the particles have an average circularity of at least 0.85 determined by image analysis. Finally, the invention relates to a slurry of microfine ilmenite.