Microfluidic Chip for Fuel Oxidation Stability Measurement

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Solution Overview

Problem

Current methods lack a certified technique for measuring the thermal stability and deposit formation of diesel fuels under dynamic conditions, with existing equipment being bulky, difficult to interpret, and not representative of real-world engine configurations, and existing microfluidic devices are complex due to ozone injection requirements.

Innovation Solution

A miniaturized microfluidic device that replicates the physical phenomena of fuel injection and circulation in internal-combustion engines or aircraft reactors, using microchannels with diameter restrictions and diversion channels to measure oxidation and thermal stability, equipped with flowmeters, pressure sensors, and spectrometers to assess fuel degradation and deposit formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional thermal stability testing equipment (JFTOT) is used, then measurement capability is achieved, but device size becomes bulky and complexity increases

Engineering Contradiction:
Improvethermal stability measurement capabilityVSAvoidequipment size and complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The conventional JFTOT device is segmented and miniaturized into a microfluidic chip platform. The fuel circulation system, heating elements, and measurement components are integrated at the micro-scale, dividing the large-scale equipment into compact functional modules that maintain measurement capability while dramatically reducing overall device size and complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A simplified microfluidic version of the JFTOT system is created that copies the essential functional principles (fuel circulation through heated channels, deposit formation, measurement) at a reduced scale. This micro-copy maintains the core measurement capability while eliminating the bulk and complexity of the original equipment.

Inventive Principle:
Principle #26Copying

2Measurement precision

If conventional JFTOT method is used, then thermal stability measurement is achieved, but results are not representative of real engine conditions

Engineering Contradiction:
Improvethermal stability measurementVSAvoidrepresentativeness of real-world conditions
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The microfluidic chip incorporates localized features that replicate specific engine conditions, such as restricted microchannels that simulate injector geometries and high-velocity flow regions. These local structural qualities create flow patterns, shear stresses, and thermal gradients that mirror real engine environments, making the measurement results representative of actual operating conditions.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The device enables precise control and variation of critical parameters (temperature, pressure, flow velocity, residence time) to match real engine operating conditions. By adjusting these parameters, the system can simulate different engine scenarios (idle, cruising, high-load) and produce results that are representative of various real-world conditions.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If microfluidic chip with unique pattern is used, then device size is reduced, but physical phenomena representation becomes inaccurate

Engineering Contradiction:
Improvedevice size reductionVSAvoidphysical phenomena reproduction accuracy
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The microfluidic chip uses dimensional scaling to reproduce physical phenomena. By transitioning from macro-scale to micro-scale dimensions, the device maintains geometric similarity while achieving compact size. The microchannel dimensions, flow rates, and thermal parameters are scaled appropriately to preserve the fundamental physical relationships (Reynolds number, Nusselt number, etc.) that govern fuel behavior in real engines.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

4Adaptability or versatility

If ozone injection is added to microfluidic device, then oxidation testing capability is achieved, but device complexity increases

Engineering Contradiction:
Improveoxidation testing capabilityVSAvoiddevice complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The microfluidic chip is designed as a universal platform that can perform both thermal stability and oxidation stability testing. By integrating multiple testing capabilities into a single device architecture, the system achieves versatility without proportionally increasing complexity. The same microchannel network and measurement systems serve both thermal and oxidation test modes.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The device incorporates ozone injection capability to enable accelerated oxidation testing. Ozone, as a strong oxidant, enhances the oxidation rate in the microfluidic system, allowing oxidation stability measurements to be obtained more quickly and efficiently. This feature is integrated into the existing microfluidic architecture, adding oxidation testing capability while leveraging the compact design.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device provides a compact, representative, and accurate measurement of fuel stability and deposit formation, capable of simulating real-world conditions, reducing equipment size and complexity while requiring less fuel and a secure environment.

Implementation Method 1

The microchannels comprises representation of the at least one of the injection and the circulation of the fuel

Methodology Applied
Scientific EffectShear stress: Shear Stress

Implementation Method 2

the physical phenomena to which fuels are subjected are reproduced by the microchannels

Methodology Applied
Scientific EffectTurbulence: Turbulence

Implementation Method 3

measuring at least one of the oxidation stability and the thermal stability of a fuel

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 4

the formation of diesel fuel deposits under dynamic conditions

Methodology Applied
Scientific EffectDeposit formation: Deposition (physical)

Implementation Method 5

measuring at least one of the oxidation stability and the thermal stability of a fuel

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS11598761B2Device for measuring the oxidation stability and/or the thermal stability of a fuel by means of a microfluidic chip
Publication Date: 2023.03.07 IFP ENERGIES NOUVELLES
  • US11598761B2 patent drawing

AI summary

The present invention relates to a device (1) for measuring the oxidation stability and/or the thermal stability of any type of fuel, including diesel fuel, by miniaturization of the test system by use of a microfluidic technique. The physical phenomena to which fuels are subjected are reproduced by the microchannels (12) of the microfluidic chip (7), which comprise a representation of at least one of the fuel injection and the fuel circulation for a drive system, an internal-combustion engine or an aircraft reactor for example.