Micromachined Separator for Super-Capacitor Ion Transmission

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Solution Overview

Problem

The miniaturization of portable electronic devices is hindered by increasing energy requirements, and conventional super-capacitors face issues with electrode short circuits due to insulative separators that are not permeable to ions, limiting their effectiveness in energy storage.

Innovation Solution

A method of producing super-capacitors using a robust separator with micromachined holes that allow ion transmission, formed from materials like nitride or parylene, and wafer bonding to create a chamber with out-of-plane electrodes and electrolyte, preventing electrical contact while enabling ion movement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a robust insulative separator is used between electrodes, then electrical contact between electrodes is prevented, but ion transmission is blocked limiting energy storage effectiveness

Engineering Contradiction:
Improveprevention of electrode short circuitVSAvoidion transmission capability
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The separator is designed with micromachined holes penetrating through its thickness, transforming it from a solid impermeable structure to a porous one. These holes have dimensions (e.g., 2 nanometers to 5 microns) that permit ion transmission while the separator material itself maintains electrical insulation properties, thus resolving the contradiction between preventing short circuits and allowing ion flow.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The separator combines two key properties: electrical insulation from materials like nitride or parylene, and ion permeability through micromachined holes. This composite structure integrates the beneficial properties of insulative materials with the transport capability of porous structures, enabling simultaneous achievement of electrical isolation and ionic conduction.

Inventive Principle:
Principle #40Composite materials

2Reliability

If separator material is made substantially impermeable to ions, then electrical insulation is enhanced, but ion movement is restricted reducing super-capacitor performance

Engineering Contradiction:
Improveelectrical insulationVSAvoidenergy storage capacity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The separator is segmented into solid insulative regions and hollow hole regions. The solid portions provide electrical insulation while the hollow holes provide ion transport pathways. This segmentation allows the separator to perform both functions simultaneously without compromise.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the separator have different properties: the bulk material provides electrical insulation while the micromachined holes provide ion permeability. This local differentiation of properties allows the separator to satisfy both electrical insulation and ion transmission requirements in different locations of the same component.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the energy storage capacity and reliability of super-capacitors by allowing free ion movement through the separator, addressing the limitations of prior art separators and enabling efficient energy storage in compact devices.

Implementation Method 1

The holes are sized to permit transmission of the ions of the electrolyte through the holes

Methodology Applied
Scientific EffectIon transmission through micropores: Porosity

Implementation Method 2

wafer bond the first substrate to the second substrate

Methodology Applied
Scientific EffectWafer bonding: Welding

Data Source

PatentUS9601278B2Super-capacitor with separator and method of producing the same
Publication Date: 2017.03.21 ANALOG DEVICES INC
  • US9601278B2 patent drawing
  • US9601278B2 patent drawing
  • US9601278B2 patent drawing

AI summary

A method of producing a super-capacitor provides a first substrate having a first base, forms a first electrode on the first substrate, and forms a separator so that the electrode is between the first base and the first separator. The method also micromachines holes through the separator, forms a chamber, and adds electrolyte, having ions, to the chamber. The electrolyte is in contact with the first electrode within the chamber. In addition, the holes are sized to permit transmission of the ions of the electrolyte through the holes.