Micronized Starch Particle Size and Crystallinity Retention

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Solution Overview

Problem

Native starches have limitations in industrial applications due to insolubility in cold water, loss of viscosity, and thickening power after cooking, which are not effectively addressed by existing physical modification methods.

Innovation Solution

Micronization of starch to achieve an average particle size of less than 5 µm with a degree of polymerization greater than 100, while maintaining at least 20% crystallinity of the base granular starch, using dehydration and micronization in an oxygen-free environment to enhance water solubility and structural integrity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If physical modification methods are used to improve water solubility, then water solubility is improved, but viscosity and thickening power are lost

Engineering Contradiction:
Improvewater solubilityVSAvoidviscosity and thickening power
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The starch granules are segmented into smaller particles through micronization, reducing particle size to less than 5 μm. This segmentation increases the surface area to volume ratio, improving water solubility while preserving the molecular structure necessary for viscosity and thickening power.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the particle size parameter of starch from larger granular form to micronized form with average particle size less than 5 μm. This parameter change improves water solubility while the controlled degree of polymerization (>100) and retained crystallinity (>20%) preserve viscosity and thickening properties.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If starch granules are reduced in size, then water solubility is improved, but crystallinity is lost

Engineering Contradiction:
Improvewater solubilityVSAvoidcrystallinity
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The micronization process applies partial action by reducing particle size to less than 5 μm without completely breaking down the crystalline structure. The controlled processing maintains at least 20% crystallinity while achieving improved water solubility through size reduction.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The patent simultaneously controls multiple parameters: particle size (reduced to <5 μm), degree of polymerization (maintained >100), and crystallinity (retained >20%). This multi-parameter control achieves water solubility improvement while preserving structural stability.

Inventive Principle:
Principle #35Parameter changes

3Length of moving object

If mechanical attrition is used to reduce particle size, then particle size is reduced, but structural integrity deteriorates

Engineering Contradiction:
Improveparticle sizeVSAvoidstructural integrity
Core Design Contradiction:
Length of moving objectVSStrength

Solution Approach 1:

The patent applies controlled parameter changes during mechanical attrition, optimizing the balance between particle size reduction and structural preservation. The process achieves average particle size less than 5 μm while maintaining degree of polymerization greater than 100 and crystallinity greater than 20%, thereby preserving structural integrity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The micronization process applies continuous useful action by progressively reducing particle size through controlled mechanical attrition without interrupting the preservation of molecular structure. This continuous process maintains the balance between size reduction and structural integrity throughout the treatment.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The micronized starch exhibits improved water solubility, retention of crystallinity, and stability, with enhanced gelatinization properties and increased crushing strength in tablet formulations, overcoming the limitations of native starches.

Implementation Method 1

Physical modification also includes mechanical attrition to alter the physical size of starch granules

Methodology Applied
Scientific EffectMechanical attrition: Abrasion

Implementation Method 2

dehydration and micronization in an oxygen-free environment to enhance water solubility and structural integrity

Methodology Applied
Scientific EffectDehydration: Desiccation

Data Source

PatentEP2644622B1Micronized starch and methods for manufacturing same
Publication Date: 2025.01.15 CORN PRODUCTS DEVELOPMENT INC
  • EP2644622B1 patent drawingFigure 1A
  • EP2644622B1 patent drawingFigure 1B
  • EP2644622B1 patent drawingFigure 1C

AI summary

The present application is related to a micronized starch with an average particle size of less than 5 µm and a degree of polymerization greater than 100, wherein the micronized starch exhibits at least 20% of the crystallinity of the base granular starch.