Microporous Carbon Monoliths for Low-Pressure Natural Gas Storage

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Solution Overview

Problem

Current high-pressure compressed natural gas systems for vehicular use are costly and pose safety risks due to the high-pressure requirements, necessitating a more efficient and safer storage solution for natural gas.

Innovation Solution

Development of high purity microporous carbon adsorbents derived from renewable natural sources, which can reversibly adsorb and desorb natural gas at significantly lower pressures, reducing storage tank costs and enhancing safety.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If high-pressure compression is used to store natural gas, then storage capacity is improved, but safety risks and system costs increase

Engineering Contradiction:
Improvenatural gas storage capacityVSAvoidsafety
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent employs microporous carbon adsorbent materials with controlled pore sizes (0.5-2 nm) that provide high surface area for gas adsorption. The porous structure enables natural gas storage at low pressures through adsorption mechanisms rather than compression, achieving high storage capacity while eliminating safety risks associated with high-pressure systems

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention changes the storage mechanism from pressure-based compression to adsorption-based retention by utilizing the surface properties of carbon materials. By controlling pore size distribution and surface chemistry parameters, the system achieves high gas capacity at atmospheric or sub-atmospheric pressures, resolving the contradiction between storage quantity and safety

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If high-pressure compression equipment is used, then natural gas storage capacity is improved, but system cost increases

Engineering Contradiction:
Improvenatural gas storage capacityVSAvoidsystem cost
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent utilizes carbon adsorbent materials with optimized pore structures that provide high gas capacity without requiring expensive compression equipment. The adsorption-based storage system eliminates costly high-pressure tanks, compressors, and safety systems, significantly reducing overall system manufacturing costs while maintaining high storage capacity

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention replaces the mechanical compression system with a chemical/physical adsorption system. Instead of using mechanical compressors and high-pressure containment systems, the patent employs carbon materials that naturally adsorb gas molecules through surface interactions, eliminating the need for expensive mechanical compression infrastructure

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The carbon adsorbents enable substantial natural gas storage at lower pressures, reducing storage tank costs and enhancing safety by allowing natural gas to be stored and dispensed efficiently and safely, thus advancing the use of natural gas as a vehicular fuel.

Implementation Method 1

a high capacity, high efficiency natural gas storage medium on which natural gas is sorptively retained in inventory

Methodology Applied
Scientific EffectPhysical adsorption: Physisorption

Implementation Method 2

from which natural gas can be readily desorbed under dispensing conditions

Methodology Applied
Scientific EffectDesorption: Desorption

Implementation Method 3

high purity microporous carbon adsorbents prepared from renewable natural sources

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Data Source

PatentUS10335763B2Microporous carbon monoliths from natural carbohydrates
Publication Date: 2019.07.02 ENTEGRIS INC
  • US10335763B2 patent drawing
  • US10335763B2 patent drawing
  • US10335763B2 patent drawing

AI summary

A carbon pyrolyzate material is disclosed, having utility as an adsorbent as well as for energy storage and other applications. The pyrolyzate material comprises microporous carbon derived from low cost naturally-occurring carbohydrate source material such as polysaccharides. In adsorbent applications, the carbon pyrolyzate may for example be produced in a particulate form or a monolithic form, having high density and high pore volume to maximize gas storage and delivery, with the pore size distribution of the carbon pyrolyzate adsorbent being tunable via activation conditions to optimize storage capacity and delivery for specific gases of interest.