Microporous Sensor Array for VOC Identification

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Solution Overview

Problem

Current methods for detecting and quantifying low-level airborne organic compounds are expensive, bulky, and require frequent calibration and maintenance, making them impractical for widespread use in identifying unknown organic compounds in gaseous media.

Innovation Solution

A method using sensor elements with a microporous material detection layer, where two sensor elements with baseline responses are exposed to different concentrations of an unknown organic compound, and the data is compared to a reference library of normalized response correlations to identify and quantify the compound, allowing for the determination of chemical identity and concentration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If mass spectroscopy is used for detecting and quantifying low-level airborne organic compounds, then measurement precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improvedetection precisionVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent employs disposable sensor elements with microporous polymer coatings that are inexpensive to manufacture and replace. These sensors use materials like polyvinylidene fluoride and polyacrylonitrile that can be applied as thin films on substrate surfaces, creating low-cost detection devices that eliminate the need for expensive, complex mass spectrometers while maintaining adequate detection precision for VOC identification

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention utilizes microporous polymer materials as the detection layer on sensor elements. These porous materials selectively absorb volatile organic compounds from air samples, enabling detection through changes in electrical properties. The microporous structure provides sufficient surface area and selectivity for VOC detection without requiring the complex instrumentation of mass spectroscopy

Inventive Principle:
Principle #31Porous materials

2Measurement precision

If mass spectroscopy is used for detecting and quantifying low-level airborne organic compounds, then measurement precision is improved, but device portability worsens

Engineering Contradiction:
Improvedetection precisionVSAvoiddevice portability
Core Design Contradiction:
Measurement precisionVSWeight of moving object

Solution Approach 1:

The patent employs disposable sensor elements with microporous polymer coatings that are inexpensive to manufacture and replace. These sensors use materials like polyvinylidene fluoride and polyacrylonitrile that can be applied as thin films on substrate surfaces, creating low-cost detection devices that eliminate the need for expensive, complex mass spectrometers while maintaining adequate detection precision for VOC identification

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention utilizes microporous polymer materials as the detection layer on sensor elements. These porous materials selectively absorb volatile organic compounds from air samples, enabling detection through changes in electrical properties. The microporous structure provides sufficient surface area and selectivity for VOC detection without requiring the complex instrumentation of mass spectroscopy

Inventive Principle:
Principle #31Porous materials

3Measurement precision

If mass spectroscopy is used for detecting and quantifying low-level airborne organic compounds, then measurement precision is improved, but maintenance requirements increase

Engineering Contradiction:
Improvedetection precisionVSAvoidmaintenance frequency
Core Design Contradiction:
Measurement precisionVSEase of repair

Solution Approach 1:

The patent employs disposable sensor elements with microporous polymer coatings that are inexpensive to manufacture and replace. These sensors use materials like polyvinylidene fluoride and polyacrylonitrile that can be applied as thin films on substrate surfaces, creating low-cost detection devices that eliminate the need for expensive, complex mass spectrometers while maintaining adequate detection precision for VOC identification

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The sensor elements are designed to be self-calibrating by comparing responses across multiple sensors with different microporous polymer coatings. Each sensor type responds differently to various VOC classes, and the system automatically identifies compounds by pattern recognition without requiring external calibration standards or frequent maintenance intervention

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the identification and quantification of unknown organic compounds using relatively simple and inexpensive equipment, effectively addressing the limitations of existing technologies by providing a cost-effective and efficient method for detecting volatile organic compounds in gaseous media.

Implementation Method 1

a detection layer comprising a microporous material disposed between the first outer layer and the second outer layer, wherein at least one of the first outer layer or the second outer layer is permeable by the unknown organic compound

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS9658198B2Method for identification and quantitative determination of an unknown organic compound in a gaseous medium
Publication Date: 2017.05.23 3M INNOVATIVE PROPERTIES CO
  • US9658198B2 patent drawing
  • US9658198B2 patent drawing
  • US9658198B2 patent drawing

AI summary

A method for identifying and quantitatively analyzing an unknown organic compound in a gaseous medium. More specifically, the method provides a gas sensor array (120a, 120b, 120c, 120d) coupled to a diluting channeling gas inlet (105) with a honeycomb configuration. Each sensor (120a, 120b, 120c, 120d) in the array receives the test gas after successive dilutions. Detected gas are identified by correlating the responses of each sensor with its associated dilution.