Microproppant Coke Fracturing Fluid for Secondary Fracture Access

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Solution Overview

Problem

Existing proppants used in hydraulic fracturing operations, such as sand, suffer from high cost and limited hydrocarbon recovery rates, and currently available microproppants are cost-prohibitive for widespread use due to high costs and limited effectiveness in reaching secondary fractures.

Innovation Solution

The use of microproppant coke particles, derived from petroleum coke fines with sizes up to 105 μm, dispersed in a fracturing fluid at concentrations of 3-480 kg/m³, effectively transport and prop open both primary and secondary fractures, enhancing hydrocarbon recovery by increasing the stimulated reservoir volume.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional proppants like sand are used in hydraulic fracturing, then the fractures can be propped open, but the cost is high and hydrocarbon recovery rate is limited

Engineering Contradiction:
Improvehydrocarbon recovery rateVSAvoidcost
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent uses coke particles, a byproduct of petroleum refining, as a disposable proppant material. These particles are designed to be used once in the fracturing operation and then discarded, eliminating the need for expensive reusable or high-performance proppants while significantly reducing costs and improving hydrocarbon recovery rates.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the physical parameters of the proppant material by using coke particles with specific size distributions (including fine particles that can reach secondary fractures) and chemical properties (oil-wet characteristics) that differ from traditional sand proppants, thereby improving fracture penetration and hydrocarbon recovery.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If microproppants are used to reach secondary fractures, then fracture penetration improves, but cost becomes prohibitive for widespread use

Engineering Contradiction:
Improvefracture penetration capabilityVSAvoidcost
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The patent employs coke particles as a low-cost alternative to expensive commercial microproppants. These particles achieve comparable or superior fracture penetration capabilities while being significantly cheaper, enabling widespread adoption in industrial hydraulic fracturing operations.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent utilizes coke particles, a waste byproduct from petroleum refining operations, as a self-service proppant material. This converts a waste stream into a valuable resource, eliminating the need to purchase expensive specialized microproppants while providing effective fracture penetration.

Inventive Principle:
Principle #25Self-service

3Productivity

If higher proppant concentrations are used to improve recovery, then stimulated reservoir volume increases, but fluid loss increases

Engineering Contradiction:
Improvestimulated reservoir volumeVSAvoidfluid loss
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent changes the chemical parameters of the proppant material by using oil-wet coke particles that are compatible with oil-based fracturing fluids. This reduces interfacial tension and minimizes fluid loss while allowing higher proppant concentrations to be used effectively, thereby increasing stimulated reservoir volume without proportionally increasing fluid loss.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Microproppant coke particles enhance hydrocarbon recovery by maintaining fractures open, reducing fluid loss, and allowing for lower treatment pressures, thereby increasing the overall effectiveness and reducing costs compared to traditional proppants.

Implementation Method 1

pumping of large quantities of fracturing fluid into a subterranean formation (e.g., a low-permeability formation) under high hydraulic pressure to promote the formation of one or more fractures

Methodology Applied
Scientific EffectHydraulic pressure: Pressure Increase

Implementation Method 2

Once the fracturing fluid has been pumped into the subterranean formation, it is desired that such proppant particles could be transported into the fractures and settle therein

Methodology Applied
Scientific EffectSedimentation: Sedimentation

Data Source

PatentUS20250237127A1Hydraulic fracturing fluid comprising microproppant COKE particles, method for making same, and hydraulic fracturing processes using same
Publication Date: 2025.07.24 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • US20250237127A1 patent drawing
  • US20250237127A1 patent drawing
  • US20250237127A1 patent drawing

AI summary

A fracturing fluid comprises a carrier fluid and coke particles. The coke particles include microproppant coke particles (e.g., petroleum coke fines) having particle sizes of at most 105 μm, where the microproppant coke particles have a total concentration of at least 3 wt % based on the total weight of the coke particles. The coke particles also have a total concentration in the fracturing fluid from 14 kilograms per cubic meter to 480 kilograms per cubic meter, based on the volume of the carrier fluid. A method includes introducing such fracturing fluid into a subterranean formation.