Expandable Microspheres in Tissue Webs for Bulk

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Solution Overview

Problem

Producing premium quality soft tissue sheets with adequate softness, bulk, and strength is challenging for conventional tissue machines without the expense of a layered headbox or throughdryer, as existing methods often compromise on softness or strength to achieve bulk.

Innovation Solution

Incorporating expandable microspheres mixed with a polyvinyl alcohol stabilized vinyl acetate-ethylene copolymer dispersion into the tissue web, eliminating the need for cationic retention aids and enhancing bulk without reducing softness or strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of stationary object

If embossing is used to increase bulk, then bulk is improved, but sheet strength is reduced below acceptable levels

Engineering Contradiction:
ImprovebulkVSAvoidsheet strength
Core Design Contradiction:
Volume of stationary objectVSStrength

Solution Approach 1:

Expandable microspheres act as intermediary elements between fibers, providing bulk through their expansion capability while the polyvinyl alcohol stabilized vinyl acetate-ethylene copolymer serves as a binding mediator that maintains sheet strength. The microspheres expand to create void space for bulk without compromising the fiber network integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the physical state parameter of the microspheres from compressed (in the dry state during manufacturing) to expanded (after exposure to moisture), thereby increasing bulk without affecting the fundamental fiber structure and strength properties of the sheet.

Inventive Principle:
Principle #35Parameter changes

2Strength

If basis weight is reduced to decrease stiffness, then softness is improved, but multiple plies are required to maintain caliper and performance

Engineering Contradiction:
ImprovesoftnessVSAvoidnumber of plies
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The invention changes the bulk parameter through microsphere expansion rather than reducing basis weight, allowing single-ply sheets to achieve adequate caliper and performance. This eliminates the need for multiple plies while maintaining softness.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If cationic retention aids are used to improve retention and distribution of expandable microspheres, then retention is improved, but product complexity and cost increase

Engineering Contradiction:
Improveretention and distributionVSAvoidproduct complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The polyvinyl alcohol stabilized vinyl acetate-ethylene copolymer acts as an intermediary that facilitates the retention and distribution of expandable microspheres without requiring cationic retention aids. This polymer-stabilized dispersion system simplifies the formulation while achieving reliable microsphere incorporation.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Volume of stationary object

If conventional methods are used to achieve bulk, then bulk is improved, but softness is compromised

Engineering Contradiction:
ImprovebulkVSAvoidsoftness
Core Design Contradiction:
Volume of stationary objectVSStrength

Solution Approach 1:

Expandable microspheres serve as intermediary elements that increase bulk through internal expansion rather than external compression, preserving the soft, airy feel of the sheet. The microspheres create void space without densifying the fiber structure, thereby maintaining softness while achieving bulk.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves a significant increase in bulk by up to 10% compared to sheets without microspheres, maintaining softness and strength, and can produce tissue webs with basis weights of at least 10 gsm and bulk of at least 10 cc/g, suitable for premium tissue products.

Implementation Method 1

expandable microspheres

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 2

expandable microspheres

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

polyvinyl alcohol stabilized vinyl acetate-ethylene copolymer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 4

nonionic surfactant

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentEP2880218B1High bulk tissue comprising expandable microspheres
Publication Date: 2018.06.13 KIMBERLY CLARK WORLDWIDE INC
  • EP2880218B1 patent drawingFigure 1A~2B

AI summary

The disclosure relates to high bulk tissue webs containing microspheres. To form the tissue webs, a nonionic polymer dispersion, such as polyvinyl alcohol stabilized vinyl acetate-ethylene copolymer dispersion, is mixed with microspheres and incorporated into tissue webs to increase sheet bulk.