Microstructured Device Manufacturing via Ink Sublimation

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Solution Overview

Problem

Existing methods for manufacturing microstructured devices, such as microfluidic devices, face challenges in removing patterns without causing mechanical stress or deformation, and are limited to specific types of inks and applications, particularly requiring openings for pattern evacuation.

Innovation Solution

A method involving printing a non-solid ink on a substrate that solidifies to form a pattern, enveloping it with a non-crosslinked polymer capable of crosslinking, and then sublimating or evaporating the ink to create microstructures, allowing for a broader range of materials and applications, including those forming cavities without openings.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a jet of fluid under high pressure is used to remove the pattern, then the pattern elimination is effective, but mechanical stresses are applied to the substrate and envelope causing unsealing or deformation

Engineering Contradiction:
Improvepattern elimination efficiencyVSAvoiddevice sealing integrity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent replaces the mechanical jet of fluid approach with a thermal field approach. The pattern material is designed to decompose or evaporate when exposed to controlled heating, eliminating the need for high-pressure fluid jets that cause mechanical stress. This substitution of mechanical removal with thermal decomposition resolves the contradiction between effective pattern elimination and device integrity preservation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical and chemical parameters of the pattern material by selecting materials with specific decomposition temperatures. By choosing pattern materials that decompose at controlled temperatures below the envelope's thermal degradation point, the method enables effective pattern removal through thermal parameter control without mechanically stressing the device structure.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If a jet of fluid is used to evacuate the pattern, then microfluidic channels can be formed, but the method cannot be applied when the pattern serves to form a cavity without openings

Engineering Contradiction:
Improveapplication rangeVSAvoidprocess complexity
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent replaces the fluid evacuation mechanism with a thermal decomposition mechanism. Instead of requiring fluid jets to remove pattern material through openings, the pattern material itself is designed to decompose or evaporate in situ when heated. This allows cavity formation without requiring openings or complex fluid evacuation systems, greatly expanding applicability to both microfluidic channels and closed cavities.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes phase transitions of the pattern material, specifically decomposition and evaporation, to eliminate the pattern. By selecting pattern materials that undergo these phase transitions at controlled temperatures, the method enables pattern removal regardless of whether openings are present, allowing formation of both channels and sealed cavities through thermal processing alone.

Inventive Principle:
Principle #36Phase transitions

3Reliability

If a particular type of ink (organic paraffin-type paste) is used, then the risk of unsealing or deforming the device is reduced, but the types of devices that can be obtained are limited

Engineering Contradiction:
Improvedevice sealing integrityVSAvoiddevice type variety
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent establishes a universal platform where the envelope material and processing parameters can be adapted to support multiple pattern material types. By designing the envelope from materials with appropriate thermal stability and selecting pattern materials based on their decomposition characteristics rather than using a single fixed type, the method becomes versatile enough to produce various device types including microfluidic devices, acoustic devices, and optical devices while maintaining reliability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent enables versatility by changing the chemical and thermal parameters of both the pattern material and envelope material. Different pattern materials with varying decomposition temperatures can be selected based on the desired device type, and the envelope material is chosen or modified to provide appropriate thermal stability. This parameter-based approach allows the same fundamental process to produce diverse device types while maintaining sealing integrity through controlled thermal processing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reduces the risk of device unsealing or deformation, expands the range of materials and applications beyond microfluidics, and enables the creation of microstructures like channels and cavities without the need for openings, enhancing manufacturing flexibility and precision.

Implementation Method 1

printing a non-solid ink on the substrate, the ink solidifying on contact with the substrate to form a negative pattern

Methodology Applied
Scientific EffectSolidification: Freezing

Implementation Method 2

enveloping the ink in solid form with a non-crosslinked polymer and comprising an additive capable of allowing crosslinking of said polymer

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 3

sublimating or, depending on the nature of the ink, liquefying then evaporating the ink so as to form the microstructured device

Methodology Applied
Scientific EffectSublimation: Sublimation

Implementation Method 4

said polymer having a melting temperature strictly higher than the sublimation or evaporation temperature of the ink forming the pattern

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentEP3697727B1Method for manufacturing a microstructured device
Publication Date: 2023.06.07 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP3697727B1 patent drawingFigure 1~2
  • EP3697727B1 patent drawingFigure 3~4

AI summary

The invention relates to a method for manufacturing a microstructured device comprising the following steps: a) supplying a substrate; b) printing a non-solid ink on the substrate, the ink solidifying in contact with the substrate in order to form a negative pattern of at least one microstructure of the microstructured device to be manufactured; c) covering the ink in solid form with a polymer that is non-crosslinked and comprises an additive able to allow crosslinking of said polymer, said polymer being immiscible with the pattern obtained in step b) in order to form a cover for the pattern, said polymer having a melting temperature that is strictly greater than the sublimation or evaporation temperature of the ink forming the pattern; d) crosslinking the cover; then e) subliming or, depending on the type of ink, liquefying then evaporating the ink so as to form the microstructured device comprising said at least one microstructure. The invention also relates to devices for implementing the method according to the invention.