3D Microstructure Production via Shell-Structure Molding

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Solution Overview

Problem

Existing methods for producing three-dimensional microstructures face limitations in precision, resolution, and height due to the properties of positive and negative resists, particularly in achieving well-defined structures beyond a few 10 μm height and finer details than 500 nm with required quality.

Innovation Solution

The method involves creating a shell-structure within the target material as a matrix for molding, using spatially resolved exposure of a source material to generate a hollow structure that encases the microstructure, allowing for higher resolution and reduced writing time, and enabling the use of various materials and structural forms for enhanced functionality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If positive resists are used for three-dimensional exposure, then chemical bonds disintegrate selectively in the focus enabling 3D structure formation, but the resist cannot form well-defined structures with height more than a few 10 μm and shows relatively low resolution for structures finer than approximately 500 nm

Engineering Contradiction:
Improveresolution and height of microstructuresVSAvoidquality of source structure
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the material parameter from positive resist to negative resist, which fundamentally alters the exposure mechanism. Negative resists polymerize upon exposure rather than disintegrating, enabling the formation of well-defined three-dimensional structures with heights exceeding a few 10 μm and resolutions finer than 500 nm, thus resolving the contradiction between manufacturing precision and reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent inverts the conventional approach by using negative resists instead of positive resists. This inversion changes the fundamental mechanism: instead of removing exposed material (positive resist), the exposed material is retained and unexposed material is removed (negative resist), enabling superior 3D structure formation with high resolution and height while maintaining source structure quality

Inventive Principle:
Principle #13The other way round (Inversion)

2Manufacturing precision

If negative resists are used to overcome height limitations, then the entire volume of the resists must be exposed except for areas to be separated, but the exposure period increases significantly

Engineering Contradiction:
Improveheight of microstructuresVSAvoidexposure period
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent applies preliminary action by first writing a three-dimensional source structure in the negative resist using focused laser exposure, then forming a shell structure around it. This preliminary structuring enables selective exposure strategies where only specific regions need to be exposed subsequently, dramatically reducing the total exposure period compared to exposing the entire resist volume

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent segments the exposure process into distinct stages: first exposing and developing the source structure, then forming a shell, and finally exposing only the remaining unexposed areas through the shell. This segmentation allows parallel or sequential processing of different regions, minimizing total exposure time while achieving the required height and precision

Inventive Principle:
Principle #1Segmentation

3Length of stationary object

If repeated applications are used to multiply source structure height, then height can be increased, but the complexity increases with reduced quality of the source structure

Engineering Contradiction:
Improveheight of source structureVSAvoidcomplexity of repeated applications
Core Design Contradiction:
Length of stationary objectVSDevice complexity

Solution Approach 1:

The patent transitions from sequential layer-by-layer building (one dimension of complexity accumulation) to three-dimensional direct writing followed by shell formation (adding a spatial dimension for structure organization). This allows height extension without proportional increase in process complexity, as the shell structure provides a framework that maintains source structure quality while enabling greater heights

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of microstructures with greater precision, higher resolution, and increased height, from 0.1 μm to 1 mm, while reducing complexity and increasing the range of possible applications, particularly in MEMS, by allowing targeted motion and material selection for the microstructure.

Implementation Method 1

The exposure of positive resists leads to a chemical or physical change at the exposed site. This change may develop for example by the disintegration of chemical bonds. In order to allow the production of three-dimensional structures the light source is focused in the positive resist, namely such that the chemical bonds of the resist are only disintegrated in the focus. This can be achieved by a non-linear effect, i.e. either the resist reacts non-linear and shows a limit of light intensity, below which no exposure may occur, or the method of the two- or multi-photon polymerization is used

Methodology Applied
Scientific EffectMulti-photon absorption:

Implementation Method 2

Subsequently, an electrolyte gold is galvanically precipitated into these hollow spaces

Methodology Applied
Scientific EffectGalvanic precipitation: Electroplating

Data Source

PatentUS8986563B2Method for the production of three-dimensional microstructures
Publication Date: 2015.03.24 NANOSCRIBE HLDG GMBH
  • US8986563B2 patent drawing
  • US8986563B2 patent drawing
  • US8986563B2 patent drawing

AI summary

A method for producing three-dimensional microstructures in which a source material is applied on a substrate, with a property changing by exposure with electromagnetic radiation. A three-dimensional source structure is written via spatially-resolving exposure in the source material, the source material is removed except for the source structure, and the source structure is molded with a target material, from which the microstructure to be produced is made. Here, a shell structure is provided surrounding the microstructure to be produced, with the source structure being created as the shell structure or the shell structure is produced using the source structure, and subsequently the target material is inserted into the shell structure.