Continuous Microwave Depolymerization Reactor for Polyesters

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Solution Overview

Problem

Current industrial processes for depolymerizing polyesters and polyamides are not satisfactory in terms of simplicity, yield, efficiency, and speed, and lack detailed implementation guidelines for industrial-scale exploitation.

Innovation Solution

A continuous microwave depolymerization reactor with a specific configuration that allows for the efficient recovery of monomers from polyesters and polyamides, eliminating the need for melting and reducing energy costs, featuring a two-unit system for versatile operation and minimal reactant waste.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional depolymerization methods are used, then the process can be implemented with existing equipment, but the process complexity and cost increase significantly for industrial scale

Engineering Contradiction:
Improveease of industrial implementationVSAvoidprocess complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent replaces traditional mechanical heating systems with microwave irradiation for depolymerization. This substitution eliminates the need for complex melting and heating equipment, reducing device complexity while maintaining industrial scalability. The microwave system directly provides the energy needed for depolymerization without requiring elaborate thermal management infrastructure.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental energy delivery parameter from thermal conduction (traditional heating) to electromagnetic radiation (microwaves). This parameter change simplifies the process by enabling direct energy absorption by the polymer material, eliminating intermediate heating steps and reducing the complexity of process equipment required for industrial implementation.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If melting step is included in the process, then the polymer can be properly depolymerized, but the energy cost increases significantly

Engineering Contradiction:
Improvedepolymerization efficiencyVSAvoidenergy cost
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent performs grinding of the polymer material before depolymerization to increase surface area and facilitate direct microwave absorption. This preliminary action eliminates the need for subsequent melting, as the ground material can be directly depolymerized through microwave irradiation, significantly reducing energy costs while maintaining high depolymerization efficiency.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces the thermal melting process with microwave-induced direct depolymerization. By using microwave energy to directly break down the polymer chains in the ground material, the process eliminates the energy-intensive melting step while achieving complete depolymerization, thus reducing energy costs without sacrificing productivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If continuous processing is implemented, then the production speed increases, but the equipment complexity increases

Engineering Contradiction:
Improveprocess speedVSAvoidequipment complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent divides the continuous processing system into distinct functional segments: a grinding unit that continuously feeds ground polymer material, and a microwave irradiation chamber that continuously processes the material. This segmentation allows each unit to be relatively simple in design while achieving high overall productivity through continuous operation, avoiding the need for a single complex integrated system.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables effective and inexpensive recycling of polyesters and polyamides on an industrial scale with reduced energy costs and no melting requirement, improving process efficiency and yield compared to traditional methods.

Implementation Method 1

a) to which microwaves are provided in order to depolymerize the polymeric material in granules already mentioned

Methodology Applied
Scientific EffectMicrowave radiation: Microwave Radiation

Implementation Method 2

some polymeric materials, for example polyesters and polyamides, can be depolymerized, i.e. reduced to the form of monomers (or oligomers)

Methodology Applied
Scientific EffectDepolymerization: Decomposition (biological)

Data Source

PatentEP2736968B1Method and apparatus for the recycling of polymeric materials via depolymerization process
Publication Date: 2020.03.11 GR3N SA
  • EP2736968B1 patent drawingFigure 1
  • EP2736968B1 patent drawingFigure 2~3
  • EP2736968B1 patent drawingFigure 4~6

AI summary

In a method and an apparatus for the recycling of polymeric materials, more specifically polyesters and polyamides, via depolymerization process, the depolymerization reaction of the material to be treated is performed with a solvolytic mixture in at least one microwave depolymerization reactor (6) which extends substantially along an axis (A) and is provided with a system (7) for movement of the reactants which allows the reactor (6) to operate continuously; the movement system (7) is an Archimedean screw system which moves the reactants substantially along the axis (A) through the reactor (6).