Microwave Passivation Removal for Low-k Via Protection

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Solution Overview

Problem

Existing capacitively coupled plasma (CCP) techniques for removing passivation layers in semiconductor fabrication cause low-k carbon loss and hydrogen plasma damage to underlying layers.

Innovation Solution

A microwave assisted process is used to remove passivation layers without generating plasma, employing microwave energy to excite process gases and maintain a vacuum environment, reducing damage to underlying layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If capacitively coupled plasma (CCP) technique is used to remove passivation layer, then passivation layer removal is achieved, but low-k carbon loss and hydrogen plasma damage occur

Engineering Contradiction:
Improvepassivation layer removal efficiencyVSAvoidlow-k carbon loss and hydrogen plasma damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the fundamental parameter of the removal process by switching from plasma-based chemistry to microwave-based physical heating. This parameter change allows passivation layer removal without the harmful chemical effects of plasma, thereby eliminating low-k carbon loss and hydrogen plasma damage while maintaining removal efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the plasma-based chemical removal mechanism with a microwave-based thermal mechanism. By substituting the plasma field with microwave electromagnetic fields that generate heat through dielectric heating, the process achieves passivation layer removal without plasma-induced damage to underlying layers

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method minimizes low-k carbon loss and hydrogen plasma damage, preserving the integrity of underlying layers during passivation layer removal.

Implementation Method 1

delivering microwave energy to the process gas, wherein delivering the microwave energy to the process gas does not generate a plasma in the processing chamber

Methodology Applied
Scientific EffectDielectric heating: Dielectric Heating

Data Source

PatentUS20250273454A1Microwave assisted passivation layer removal
Publication Date: 2025.08.28 APPLIED MATERIALS INC
  • US20250273454A1 patent drawing
  • US20250273454A1 patent drawing
  • US20250273454A1 patent drawing

AI summary

A method of processing a substrate, includes performing a preclean process to form an exposed surface of a conductive layer within a via formed in a dielectric layer formed over the conductive layer, forming a passivation layer over the exposed surface of the conductive layer, and removing the passivation layer using a microwave assisted process.