Microwave Plasma Reactor for Hydrogen Production

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Solution Overview

Problem

Conventional methods for converting light hydrocarbons to hydrogen-rich gas are energy inefficient, leading to high costs in small-scale applications and susceptibility to electrode erosion in plasma fuel converters.

Innovation Solution

A plasma reactor using a low temperature, non-equilibrium plasma with a vortex flow and sliding arc discharge, where reagents are introduced to create a reverse vortex flow, increasing residence time and efficiency, and a plasma-assisted flame is used to enhance hydrogen production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If DC arc plasmatrons are used for hydrocarbon reforming, then hydrogen-rich gas can be produced, but electrode erosion and melting occur due to high current operation

Engineering Contradiction:
Improvehydrogen production rateVSAvoidelectrode durability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent replaces the conventional DC arc plasma system with a microwave plasma system. Instead of using high current electrical discharge that causes electrode erosion, the invention uses microwave radiation (electromagnetic energy) to generate plasma in a resonant cavity. This substitution of the plasma generation mechanism eliminates the mechanical/electrical contact between electrodes and plasma, thereby preventing electrode erosion and melting while maintaining hydrogen production capability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If DC arc plasmatrons operate at high current, then hydrogen production is achieved, but high power input and coolant requirements increase operational complexity

Engineering Contradiction:
Improvehydrogen production rateVSAvoidcooling system requirements
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent replaces the high current DC electrical system with a microwave electromagnetic field system. The microwave plasma generator couples energy into a resonant cavity where plasma is sustained without requiring high current flow through physical electrodes. This eliminates the need for complex cooling systems and high current power supplies, reducing operational complexity while maintaining hydrogen production efficiency.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If gliding arc electric discharges with pulsed plasma are used, then hydrocarbon conversion is achieved, but process stability deteriorates over time

Engineering Contradiction:
Improvehydrocarbon conversion rateVSAvoidprocess stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent employs periodic microwave pulsing to sustain plasma in the resonant cavity. By applying microwave energy in controlled periodic cycles, the system maintains stable plasma conditions and consistent hydrocarbon conversion rates. The periodic action allows for controlled plasma ignition and sustenance without the instability issues associated with gliding arc systems, ensuring reliable and repeatable process performance.

Inventive Principle:
Principle #19Periodic action

4Productivity

If external heat sources are used for preheating reagents, then hydrocarbon reforming is enabled, but energy efficiency decreases

Engineering Contradiction:
Improvereforming reaction rateVSAvoidenergy efficiency
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent implements a self-heating mechanism where the microwave plasma directly heats the hydrocarbon feedstock as it passes through the reaction zone. The plasma-generated heat is utilized in-situ for the reforming reactions, eliminating the need for separate external preheating systems. This self-service approach recovers and utilizes the thermal energy generated within the plasma reactor itself, significantly improving overall energy efficiency while maintaining high reforming reaction rates.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves higher energy efficiency and longer electrode life by maintaining a stable sliding arc, reducing heat loss, and optimizing plasma generation, resulting in improved hydrogen production with reduced energy input.

Implementation Method 1

creating a plasma discharge in the reaction chamber

Methodology Applied
Scientific EffectPlasma discharge: Plasma

Implementation Method 2

wherein a plasma discharge is created in the reaction chamber using a microwave generator

Methodology Applied
Scientific EffectMicrowave heating: Dielectric Heating

Implementation Method 3

a first electrode and a second electrode connected to a power source for generating a sliding arc discharge in the reaction chamber

Methodology Applied
Scientific EffectElectric arc: Electric Arc

Implementation Method 4

introducing reagents to the reaction chamber in a manner that creates a vortex flow in the reaction chamber, increasing the residence time of the reagents in the reaction chamber

Methodology Applied
Scientific EffectVortex flow: Vortex Ring

Implementation Method 5

a plasma-assisted flame is used to enhance hydrogen production

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS7867457B2Plasma reactor for the production of hydrogen-rich gas
Publication Date: 2011.01.11 CHEVRON USA INC
  • US7867457B2 patent drawing
  • US7867457B2 patent drawing
  • US7867457B2 patent drawing

AI summary

A plasma reactor (10) is provided. The plasma reactor (10) includes a reaction chamber (12) formed by a wall (13). Proximate to the first end of the reaction chamber, the plasma reactor includes a feed gas inlet (14) for creating a reverse vortex gas flow (16) in the reaction chamber. The plasma reactor (10) also includes an anode and a cathode connected to a power source for generation of an electric arc for plasma generation in said reaction chamber. The plasma reactor (10) may optionally include a movable electrode adapted for movement from a first, ignition position to a second, operational position in the reaction chamber. Also provided is a method of converting light hydrocarbons to hydrogen-rich gas, using the plasma reactor of the invention.