Microwave Waveguide for Nitride Semiconductor Film Formation

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Solution Overview

Problem

Semiconductor substrate warping due to high temperatures during nitride semiconductor formation, and damage from high-energy ions and radicals at lower temperatures during plasma decomposition of group V material gas.

Innovation Solution

A semiconductor manufacturing apparatus with a first supply part for group III elements and a second supply part for group V elements, utilizing a waveguide to irradiate microwaves to the group V element gas, generating radicals and ions with reduced kinetic energy to minimize substrate damage and warping.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the substrate is heated to more than 1000 degrees Celsius to improve NH3 decomposition efficiency, then the decomposition efficiency is improved, but the substrate warping occurs

Engineering Contradiction:
Improvedecomposition efficiencyVSAvoidsubstrate warping
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the decomposition method from thermal decomposition to plasma decomposition. By introducing microwave irradiation (2.45 GHz) to generate plasma, the group V material gas is decomposed at lower temperatures (below 1000°C), thereby maintaining substrate flatness while achieving sufficient decomposition efficiency through plasma-generated radicals and ions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal field (heating system) with a plasma field (microwave irradiation system). Instead of using high-temperature thermal energy to decompose the gas, the invention uses microwave-induced plasma to generate reactive species, thus avoiding substrate warping caused by excessive heating.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Ease of manufacture

If the group V material gas is decomposed by using shower head and stage as electrodes at 60 MHz to form nitride semiconductor, then the film formation is achieved, but the high-energy ions and radicals cause damage to the substrate

Engineering Contradiction:
Improvefilm formationVSAvoidsubstrate damage
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent changes the frequency parameter from low frequency (60 MHz or less) to high frequency (2.45 GHz microwave). This frequency change fundamentally alters the plasma characteristics, generating radicals and ions with lower kinetic energy that are less damaging to the substrate while still effective for film formation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses waveguides to introduce microwave energy into the reaction chamber, creating a plasma environment without requiring the shower head and stage to function as electrodes. This alternative approach copies the desired plasma effect while avoiding the harmful high-energy ion generation associated with low-frequency electrode-based plasma.

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The apparatus effectively forms nitride semiconductor films with reduced substrate damage and warping, achieving uniform film quality and thickness by controlling microwave frequency and waveguide arrangement to optimize radical distribution.

Implementation Method 1

a waveguide configured to irradiate a microwave to the gas including the one or more group V elements

Methodology Applied
Scientific EffectMicrowave plasma generation: Plasma

Implementation Method 2

utilizing a waveguide to irradiate microwaves to the group V element gas, generating radicals and ions with reduced kinetic energy

Methodology Applied
Scientific EffectMicrowave radiation: Microwave Radiation

Implementation Method 3

the group V material gas is decomposed into plasma separately from the group III material gas, generating ions and radicals

Methodology Applied
Scientific EffectPlasma decomposition: Plasma

Implementation Method 4

decomposes a group V material gas and an organic material gas including group III elements

Methodology Applied
Scientific EffectGas decomposition: Decomposition (biological)

Implementation Method 5

a heater configured to heat the substrate

Methodology Applied
Scientific EffectThermal heating: Heating

Data Source

PatentUS11031212B2Semiconductor manufacturing apparatus
Publication Date: 2021.06.08 TOSHIBA ELECTRONICS DEVICES & STORAGE CORPORARTION
  • US11031212B2 patent drawing
  • US11031212B2 patent drawing
  • US11031212B2 patent drawing

AI summary

A semiconductor manufacturing apparatus includes a first supply part configured to supply a gas including one or more group III elements on a substrate accommodated in a reaction chamber, a second supply part configured to supply a gas including one or more group V elements on the substrate, and a waveguide configured to irradiate a microwave to the gas including the one or more group V elements.